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Volumn 63, Issue 13, 1998, Pages 4299-4304

Regio- and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C5Me5)2Sm(thf)n

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EID: 0001034069     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9723016     Document Type: Article
Times cited : (24)

References (33)
  • 2
    • 0002446724 scopus 로고
    • Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford
    • (b) Roush, W. R. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 2, pp 1-53.
    • (1991) Comprehensive Organic Synthesis , vol.2 , pp. 1-53
    • Roush, W.R.1
  • 22
    • 0002613774 scopus 로고
    • Tabuchi, T.; Inanaga, J.; Yamaguchi, M. Chem. Lett. 1987, 2275-2278. The selectivity was improved by using propargylic phosphates instead of acetates: Mikami, K.; Yoshida, A.; Matsumoto, S.; Feng, F.; Matsumoto, Y.; Sugino, A.; Hanamoto, T.; Inanaga, J. Tetrahedron Lett. 1995, 36, 907-908.
    • (1987) Chem. Lett. , pp. 2275-2278
    • Tabuchi, T.1    Inanaga, J.2    Yamaguchi, M.3
  • 24
    • 85085780669 scopus 로고    scopus 로고
    • note
    • 5) is changed to a fluxional complex by addition of THF, which occurs through a THF adduct; see ref 8.
  • 25
    • 85085782767 scopus 로고    scopus 로고
    • 1H NMR spectra of 4a,b,d are similar to those of the monomeric complexes reported, they seem to be monomeric and separated from benzyl oxide 5 in solution; see ref 8
    • 1H NMR spectra of 4a,b,d are similar to those of the monomeric complexes reported, they seem to be monomeric and separated from benzyl oxide 5 in solution; see ref 8.
  • 26
    • 85085782847 scopus 로고    scopus 로고
    • 2, showed no definite regio- and stereospecificity in the reaction with carbonyl compounds; see: ref 4
    • 2, showed no definite regio- and stereospecificity in the reaction with carbonyl compounds; see: ref 4.
  • 28
    • 85085782324 scopus 로고    scopus 로고
    • note
    • 1-complexes B by coordination of the electrophiles.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.