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We used the extrapolation technique of Zisman [W. A. Zisman, Adv. Chem. Ser. 43, 1 (1964)] in which the contact angles for sessile drops of homologous apolar liquids are plotted as a function of their liquid-vapor interfacial energy (Formula presented) To measure the contact angles, we used an optical method described in detail elsewhere (Ref. 6). We also used a remote-computer controlled goniometer system (DIGIDROP by GBX, France) to measure water contact angles greater than 90° on silanized surfaces, values for which the above method cannot be used. Advancing and receding angles were measured using a tilted sample holder table. All measurements (both techniques) were made in ambient atmosphere and at room temperature.
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EELS experiments were performed with a homemade system using a cylindrical mirror analysis (CMA). The samples are bombarded with a primary electrons at (Formula presented) normal incidence, and in a standard single-pass CMA pulse counting mode. We applied an EELS procedure describe in P. Poveda and A. Glachant, Surf. Sci. 323, 258 (1995).
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