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A general treatment of both the computational and experimental aspects of siliconate formation has recently been published. Damrauer, R.; Burggraf, L. W.; Davis, L. P.; Gordon, M. S. J. Am. Chem. Soc. 1988, 110, 6601
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The ease of silane cleavage with base in solution correlates with the basicity of the carbanion being expelled; see
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This method of determining the relative basicities of ions is similar, in principle, to the method of Cooks and co-workers in which cluster ions are given internal energy by collisions in a mass spectrometer
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This method of determining the relative basicities of ions is similar, in principle, to the method of Cooks and co-workers in which cluster ions are given internal energy by collisions in a mass spectrometer: Wright, L. G.; McLuckey, S. A.; Cooks, R. G.; Wood, K. V. Int. J. Mass Spectrom. Ion Phys. 1982, 42, 115.
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We have carried out MM2 force field calculations on tert-butyltrimethylsilane using the recently published parameters that have been extended to silicon (Frierson, M. R.; Imam, M. R.; Zalkow, V. B.; Allinger, N. L. J. Org. Chem. 1988, 53, 5248). We found that tert-butyltrimethylsilane is strain free
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Ouellette, R. J.; Baron, D.; Stolfo, J.; Rosenblum, A.; Weber, P. Tetrahedron 1972, 28, 2163. We have carried out MM2 force field calculations on tert-butyltrimethylsilane using the recently published parameters that have been extended to silicon (Frierson, M. R.; Imam, M. R.; Zalkow, V. B.; Allinger, N. L. J. Org. Chem. 1988, 53, 5248). We found that tert-butyltrimethylsilane is strain free.
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in press For other recent studies of bond dissociation energies see: Russell, J. J.; Seetula, J. A.; Gutman, D. J. Am. Chem. Soc. 1988, 110, 3092. Russell, J. J.; Seetula, J. A.; Timonen, R. S.; Gutman, D.; Nava, D. F. J. Am. Chem. Soc. 1988, 110, 3084
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Griller, D.; Kanabus-Kaminska, J. M.; Maccoll, A. J. Mol. Struct., in press. For other recent studies of bond dissociation energies see: Russell, J. J.; Seetula, J. A.; Gutman, D. J. Am. Chem. Soc. 1988, 110, 3092. Russell, J. J.; Seetula, J. A.; Timonen, R. S.; Gutman, D.; Nava, D. F. J. Am. Chem. Soc. 1988, 110, 3084.
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