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Tetrahedron Letters

Volumn 20, Issue 42, 1979, Pages 4087-4090

Introduction of functionalized substituents into active methylene compounds

(2) Hori, Isaburo a Oishi, Takeshi a

a INST OF PHYS AND CHEMICAL RESEARCH (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001012273 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(01)86511-4 Document Type: Article

Times cited : (14)

References (18)

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6
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- Chemistry of acetylenic ethers XLII: A simplified method for the preparation of acetylenic thioethers; a number of new reactions of these compounds
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7
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8
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9
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- Reaction of .alpha.,.beta.-ethylenic sulfur compounds with organocopper reagents
- (1973) The Journal of Organic Chemistry , vol.38 , pp. 2747
- Posner¹ Brunelle²

10
- 84984028634
- Chemistry of acetylenic ethers 105. Addition of organocopper(I) reagents to 1-alkynyl sulfoxides
- (1974) Recueil des Travaux Chimiques des Pays-Bas , vol.93 , pp. 240
- Vermeer¹ Meijer² Eylander³

11
- 0001129934
- (1974) J. Org. Chem. , vol.39 , pp. 3174
- Truce¹ Lusch²

12
- 0000874688
- (1978) J. Org. Chem. , vol.43 , pp. 2252
- Truce¹ Lusch²

13
- 0001836294
- A Useful Route for Olefin Synthesis: Thermolysis of the Michael Adducts of Aryl Vinyl Sulfoxides
- Condensation of 1-bromovinyl p-chlorophenyl sulfoxide with 2-nitropropane and subsequent dehydrobromination has been published;, Addition of MeOH to the product and the subsequent thermolysis has also been reported.
- (1977) Synthesis , pp. 299
- Tanikaga¹ Sugihara² Tanaka³ Kaji⁴

14
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- (1974) Tetrahedron Lett. , pp. 455
- Tsuchihashi¹ Mitamura² Ogura³

15
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- In the cases of 2,2-disubstituted vinyl sulfoxides (19) and (20), the isomeric 1-hydroxy-2-bromo derivatives were also obtained.

16
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- The bromovinyl derivatives are presumably produced by the cleavage of the cyclic sulfoxonium salt (i) formed from initially produced bromohydrin by taking into account of the mechanism of the related reactions;, However, a different cleavage pattern of cyclic sulfoxonium salts has been reported;
- (1973) J. Am. Chem. Soc. , vol.95 , pp. 3420
- Jung¹ Sharma² Durst³

17
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- Bromine present in i must be playing an important role in the present reaction but the exact mechanism is still open for discussion.
- (1973) Tetrahedron Lett. , pp. 2463
- Taguchi¹ Yamamoto² Nozaki³

18
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- ++ 1” peaks were observed for all substituted diethyl ethylmalonates (6, 7, 8, 13a,b, and 15) we examined.

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