Synthesis, structure, and fluxional behavior of base-stabilized silyl(silylene)tungsten complexes

Organometallics

Volumn 17, Issue 11, 1998, Pages 2138-2140

  Ueno, Keiji ^a   Sakai, Mihoko ^a   Ogino, Hiroshi ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001004814     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980121w     Document Type: Article

References (36)

1. Curtis, M. D.; Epstein, P. S. Adv. Organomet. Chem. 1981, 19, 213.
2. Schubert, U. Angew. Chem., Int. Ed. Engl. 1994, 33, 419.
3. Kobayashi, T.; Hayashi, T.; Yamashita, H.; Tanaka, M. Chem. Lett. 1988, 1411.
4. (a) Pannell, K. H.; Cervantes, J.; Hernandez, C.; Cassias, J.; Vincenti, S. Organometallics 1986, 5, 1056.
5. (b) Pannell, K. H.; Wang, L.-J.; Rozell, J. M. Organometallics 1989, 8, 550.
6. (c) Pannell, K. H.; Rozell, J. M., Jr.; Hernandez, C. J. Am. Chem. Soc. 1989, 111, 4482.
7. (d) Shama, H. K.; Pannell, K. H. Chem. Rev. 1995, 95, 1351.
8. (a) Tobita, H.; Ueno, K.; Ogino, H. Chem. Lett. 1986, 1777.
9. (b) Tobita, H.; Ueno, K.; Ogino, H. Bull. Chem. Soc. Jpn. 1988, 61, 2797.
10. (c) Ueno, K.; Tobita, H.; Ogino, H. Chem. Lett. 1990, 369.
11. Haynes, A.; George, M. W.; Haward, M. T.; Poliakoff, M.; Turner, J. J.; Boag, N. M.; Green, M. J. Am. Chem. Soc. 1991, 113, 2011.
12. (a) Mitchell, G. P.; Tilley, T. D.; Yap, G. P. A.; Rheingold, A. L. Organometallics 1995, 14, 5472.
13. (b) Pestana, D. C.; Koloski, T. S.; Berry, D. H. Organometallics 1994, 13, 4173.
14. (c) Tanaka, Y.; Yamashita, H.; Tanaka, M. Organometallics 1995, 14, 530.
15. (d) Tamao, K.; Sun, G.-R.; Kawachi, A. J. Am. Chem. Soc. 1995, 117, 8043.
16. (a) Ueno, K.; Tobita, H.; Shimoi, M.; Ogino, H. J. Am. Chem. Soc. 1988, 110, 4092.
17. (b) Tobita, H.; Ueno, K.; Shimoi, M.; Ogino, H. J. Am. Chem. Soc. 1990, 112, 3415.
18. (c) Takeuchi, T.; Tobita, H.; Ogino, H. Organometallics 1991, 10, 835.
19. (d) Tobita, H.; Wada, H.; Ueno, K.; Ogino, H. Organometallics 1994, 13, 2545.
20. (e) Ueno, K.; Ito, S.; Endo, K.; Tobita, H.; Inomata, S.; Ogino, H. Organometallics 1994, 13, 3309.
21. (f) Okazaki, M.; Tobita, H.; Ogino, H. Chem. Lett. 1997, 1997, 437.
22. (g) Ueno, K.; Masuko, A.; Ogino, H. Organometallics 1997, 16, 5023.
23. Nlate, S.; Herdtweck, E.; Fischer, R. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 1861.
24. Pannell, K. H.; Sharma, H. K.; Kapoor, R. N.; Cervantes-Lee, F. J. Am. Chem. Soc. 1997, 119, 9315.
25. Ueno, K.; Nakano, K.; Ogino, H. Chem. Lett. 1996, 459.
26. Malisch, W. J. Organomet. Chem. 1974, 82, 185.
27. -1. Satisfactory results of elemental analysis for complex 1b could not be obtained due to its extreme sensitivity toward air and moisture.
28. 2W: C, 35.12; H, 6.22. Found: C, 35.19; H, 6.03.
29. 16 R1 = 0.049 and wR2 = 0.105 for 3631 reflections with I > 2.0σ(I).
30. Sheldrick, G. M. SHELX-97, Program for Crystal Structure Determination; University of Göttingen: Göttingen, Germany, 1997.
31. (a) Schmitzer, S.; Weis, U.; Käb, H.; Buchner, W.; Malisch, W.; Polzer, T., Posset, U.; Kiefer, W. Inorg. Chem. 1993, 32, 303.
32. (b) Malisch, W.; Lankat, R.; Seelbach, W.; Reising, J.; Noltemeyer, M.; Pikl, R.; Posset, U.; Keifer, W. Chem. Ber. 1995, 128, 1109.
33. (c) Malisch, W.; Schmitzer, S.; Lankat, R.; Neumayer, M.; Prechtl, F.; Adam, W. Chem. Ber. 1995, 128, 1251.
34. (d) Sharma, S.; Kapoor, R. N.; Cervantes-Lee, F.; Pannell, K. H. Polyhedron 1991, 10, 1177.
35. Sheldrick, W. S. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1989; Chapter 3.
36. Zybill, C.; Handwerker, H.; Friedrich, H. Adv. Organomet. Chem. 1994, 36, 229.