Silylation-mediated oxidation of 4-aza-3-ketosteroids with DDQ proceeds via DDQ-substrate adducts

Journal of the American Chemical Society

Volumn 110, Issue 10, 1988, Pages 3318-3319

  Bhattacharya, Apurba ^a   DiMichele, Lisa M ^a   Dolling, Ulf H ^a   Douglas, Alan W ^a   Grabowski, J J ^a  

^a MERCK RESEARCH LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001002591     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00218a062     Document Type: Article

References (8)

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4. 13C studies. Silicon-29 observations were made with the INEPT technique (Burum, D. P.; Ernst, R. R. J. Magn. Reson. 1980, 39, 163–168) for optimum sensitivity. In the NMR studies a slight excess of DDQ was used, and BSTFA was added last.
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