Protonation and methylation of zerovalent molybdenum complexes of the type trans-[Mo(CNR)(L)(Ph2PCH2CH2PPh 2)2](R = Ph or Bun; L= N2, CO, or Nitrile) and trans-[Mo(CO)(L′)(Ph2PCH2CH2PPh 2)2] (L′ = N2 or Nitrile) to give carbyne

Organometallics

Volumn 19, Issue 10, 2000, Pages 2002-2011

  Seino, Hidetake ^a   Nonokawa, Daigo ^a   Nakamura, Goh ^a,b   Mizobe, Yasushi ^a,c   Hidai, Masanobu ^b  

^a INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001000766     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000049d     Document Type: Article

References (47)

1. Preparation and Properties of Molybdenum and Tungsten Dinitrogen Complexes. 67. Part 66: Seino, H.; Mizobe, Y.; Hidai, M. Bull. Chem. Soc. Jpn. 2000, 73, 631.
2. (a) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
3. (b) Bazhenova, T. A.; Shilov, A. E. Coord Chem. Rev. 1995, 144, 69.
4. (c) Leigh, G. J. Acc. Chem. Res. 1992, 25, 178, and references therein.
5. (a) Howard, J. B.; Rees, D. C. Chem. Rev. 1996, 96, 2965.
6. (b) Burgess, B. K.; Lowe, D. J. Chem. Rev. 1996, 96, 2983.
7. (c) Eady, R. R. Chem. Rev. 1996, 96, 3013, and references therein.
8. Burgess, B. K. In Molybdenum Enzymes; Spiro, T. G., Ed.; John Wiley & Sons: New York, 1985; p 161.
9. (a) Wang, Y.: Fraústo da Silva, J. J. R.; Pombeiro, A. J. L.; Pellinghelli, M. A.; Tiripicchio, A.; Henderson, R. A.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1995, 1183. See also to refer to the protonation on the related isocyanide complexes: Henderson, R. A.; Pombeiro, A. J. L.; Richards, R. L.; Fraústo da Silva, J. J. R.; Wang, Y. J. Chem. Soc., Dalton Trans. 1995, 1193.
10. (a) Wang, Y.: Fraústo da Silva, J. J. R.; Pombeiro, A. J. L.; Pellinghelli, M. A.; Tiripicchio, A.; Henderson, R. A.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1995, 1183. See also to refer to the protonation on the related isocyanide complexes: Henderson, R. A.; Pombeiro, A. J. L.; Richards, R. L.; Fraústo da Silva, J. J. R.; Wang, Y. J. Chem. Soc., Dalton Trans. 1995, 1193.
11. (b) Formation of the aminocarbyne ligand has also been observed for the protonation reactions of a wider range of isocyanide complexes. See ref 16.
12. Seino, H.; Tanabe, Y.; Ishii, Y.; Hidai, M. Inorg. Chim. Acta 1998, 280, 163.
13. Chatt, J.; Leigh, G. J.; Neukomm, H.; Pickett, C. J.; Stanley, D. R. J. Chem. Soc., Dalton Trans. 1980, 121.
14. (a) Pombeiro, A. J. L.; Richards, R. L. Transition Met. Chem. 1980, 5, 55.
15. (b) Chatt, J.; Pombeiro, A. J. L.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1979, 1585.
16. Chatt, J.; Heath, G. A.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1974, 2074.
17. Tatsumi, T.; Hidai, M.; Uchida, Y. Inorg. Chem. 1975, 14, 2530.
18. Hidai, M.; Komori, K.; Kodama, T.; Jin, D.-M; Takahashi, T.; Sugiura, S.; Uchida, Y.; Mizobe, Y. J. Organomet. Chem. 1984, 272, 155.
19. (a) Seino, H.; Arita, C.; Nonokawa, D.; Nakamura, G.; Harada, Y.; Mizobe, Y.; Hidai, M. Organometallics 1999, 18, 4165.
20. (b) Nakamura, G.; Harada, Y.; Arita, C.; Seino, H.; Mizobe, Y.; Hidai, M. Organometallics 1998, 17, 1010.
21. Sato, M.; Tatsumi, T.; Kodama, T.; Hidai, M.; Uchida, T.; Uchida, Y. J. Am. Chem. Soc. 1978, 100, 4447.
22. Tatsumi, T.; Tominaga, H.; Hidai, M.; Uchida, Y. J. Organomet. Chem. 1980, 199, 63.
23. Hidai, M.; Kodama, T.; Sato, M.; Harakawa, M.; Uchida, Y. Inorg. Chem. 1976, 15, 2694.
24. (a) Mayr, A.; Hoffmeister, H. Adv. Organomet. Chem. 1991, 32, 227.
25. (b) Mayr, A.; Bastos, C. M. Prog. Inorg. Chem. 1992, 40, 1.
26. (c) Filippou, A. C. In Organic Synthesis via Organometallics; Helmchen, G., Dibo, J., Flubacher, D., Wiese, B., Eds.; F. Vieweg & Sohn: Braunschweg, 1997; p 97.
27. Carvalho, M. F. N. N.; Pombeiro, A. J. L.; Bakalbassis, E. G.; Tsipis, C. A. J. Organomet. Chem. 1989, 371, C26.
28. 2O molecule at the site trans to the aminocarbyne ligands, although full characterization was unsuccessful.
29. Fischer, E. O.; Wittman, D.; Himmelreich, D.; Cai, R.; Ackermann, K.; Neugebauer, D. Chem. Ber. 1982, 115, 3152.
30. Allen, S. R.; Beevor, R. G.; Green, M.; Orpen, A. G.; Paddick, K. E.; Williams, I. D. J. Chem. Soc., Dalton Trans. 1987, 591.
31. (a) Kim, H. P.; Angelici, R. J. Adv. Organomet. Chem. 1987, 27, 51.
32. (b) Gallop, M. A.; Roper, W. R. Adv. Organomet. Chem. 1986, 25, 121.
33. Windmüller, B.; Nürnberg, O.; Wolf, J.; Werner, H. Eur. J. Inorg. Chem. 1999, 613.
34. Esteruelas, M. A.; Lahoz, F. J.; López, A. M.; Oñate, E.; Oro, L. A. Organonetallics 1994, 13, 1669.
35. Hidai, M.; Mizobe, Y.; Sato, M.; Kodama, T.; Uchida, Y. J. Am. Chem. Soc. 1978, 100, 5740.
36. Torraca, K. E.; Ghiviriga, I.; McElwee-White, L. Organometallics 1999, 18, 2262.
37. Mayr, A.; Asaro, M. F.; Kjelsberg, M. A.; Lee, K. S.; Van Eugen, D. Organometallics 1987, 6, 432.
38. Wengrovius, J. H.; Schrock, R. R.; Churchill, M. R.; Wasserman, H. J. J. Am. Chem. Soc. 1982, 104, 1739.
39. Holmes, S. J.; Clark, D. N.; Turner, H. W.; Schrock, R. R. J. Am. Chem. Soc. 1982, 104, 6322.
40. Jeffery, J. C.; Weller, A. S. J. Organomet. Chem. 1997, 548, 195.
41. Carnahan, E. M.; Lippard, S. J. J. Chem. Soc., Dalton Trans. 1991, 699.
42. Nakamura, G.; Harada, Y.; Mizobe, Y.; Hidai, M. Bull. Chem. Soc. Jpn. 1996, 69, 3305.
43. Yoshida, T.; Hirotsu, K.; Higuchi, T.; Otsuka, S. Chem. Lett. 1982, 1017.
44. Datta, S.; Dezube, B.; Kouba, J. K.; Wreford, S. S. J. Am. Chem. Soc. 1978, 100, 4404.
45. Chatt, J.; Pombeiro, A. J. L.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1980, 492.
46. teXsan: Crystal Structure Analysis Package; Molecular Structure Corp.: The Woodlands, TX, 1985 and 1992.
47. PATTY: Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; Garcia-Granda, S.; Gould, R. O.; Smits, J. M. M.; Smykalla, C. The DIKDIF program system; Technical Report of the Crystallography Laboratory; University of Nijmegen: The Netherlands, 1992.