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As boundary conditions for the solution of the force between the electrode and the sphere, we assume that the gold mesh is at constant potential, since this electrode is potentiostated, but that the silver particle surface charge remains constant during approach to the electrode. The force is then integrated using the Derjaguin approximation, valid since κα = 7-10.
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During the course of this study, a series of papers involving voltammetry of metal oxide colloids and suspensions was published by Heyrovsky and co-workers (Langmuir 1995, 11, 4288). They also showed that multielectron transfer occurred in semiconductor dispersions.
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