Variable coordination modes for 1,1′-bis (diphenylphosphino) ferrocene (dppf) mono-and di-chalcogenides or -oxides (dppfE and dppfE2; E = O, S or Se) in copper(I) complexes. Crystal structure of [{Cu(dppf)}2(μdppfS2)] (BF4)2 and [Cu(dppfSe)2]BF4

Inorganica Chimica Acta

Volumn 277, Issue 2, 1998, Pages 163-170

  Pilloni, Giuseppe ^a   Longato, Bruno ^a,b   Bandoli, Giuliano ^c  

^a Metallorganica ed Analitica dell'Università   (Italy)

^b CNR   (Italy)

^c Dipto di Scienze Farmaceutiche   (Italy)

Author keywords

Chalcogenide complexes; Copper complexes; Crystal structures; Ferrocene complexes

Indexed keywords

BROMINE COMPOUNDS; CHALCOGENIDES; CHELATION; CHLORINE COMPOUNDS; COORDINATION REACTIONS; CRYSTAL STRUCTURE; IRON COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; PHOSPHORUS COMPOUNDS; SELENIUM COMPOUNDS; SINGLE CRYSTALS; SULFUR COMPOUNDS;

BIS(DIPHENYLPHOSPHINO) FERROCENE; COORDINATION GEOMETRY; COPPER (I) COMPLEXES; COPPER COMPLEXES; FERROCENES; SINGLE CRYSTAL X-RAY STRUCTURES; TETRAHEDRAL GEOMETRY; VARIABLE COORDINATION;

COPPER COMPOUNDS;

EID: 0000999288     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)06129-x     Document Type: Article

References (23)

1. G. Pilloni, B. Longato, G. Bandoli and B. Corain, J. Chem. Soc., Dalton Trans., (1997) 819.
2. (a) G. Pilloni, B. Corain, M. Degano, B. Longato and G. Zanotti, J. Chem. Soc., Dalton Trans., (1993) 1777;
3. (b) G. Pilloni, G. Valle, C. Corvaja, B. Longato and B. Corain, Inorg. Chem., 34 (1995) 5910.
4. See, for example, N. Burford, B.W. Royan and R.E.v.H. Spence, J. Chem. Soc., Dalton Trans., (1990) 2111; N. Burford, Coord. Chem. Rev., 112 (1992) 1; D.G. Gilheany, in F.R. Hartley (ed.), The Chemistry of Organophosphorus Compounds, Vol. 2, Wiley-Interscience, 1992, Ch. 1 and Refs, therein.
5. See, for example, N. Burford, B.W. Royan and R.E.v.H. Spence, J. Chem. Soc., Dalton Trans., (1990) 2111; N. Burford, Coord. Chem. Rev., 112 (1992) 1; D.G. Gilheany, in F.R. Hartley (ed.), The Chemistry of Organophosphorus Compounds, Vol. 2, Wiley-Interscience, 1992, Ch. 1 and Refs, therein.
6. See, for example, N. Burford, B.W. Royan and R.E.v.H. Spence, J. Chem. Soc., Dalton Trans., (1990) 2111; N. Burford, Coord. Chem. Rev., 112 (1992) 1; D.G. Gilheany, in F.R. Hartley (ed.), The Chemistry of Organophosphorus Compounds, Vol. 2, Wiley-Interscience, 1992, Ch. 1 and Refs, therein.
7. See, for example, T.S. Lobana, in F.R. Hartley (ed.), The Chemistry of Organophosphorus Compounds, Vol. 2, Wiley-Interscience, 1992, Ch. 8, and Refs. therein; J.R. Black and W. Levason, J. Chem. Soc., Dalton Trans., (1994) 3225.
8. See, for example, T.S. Lobana, in F.R. Hartley (ed.), The Chemistry of Organophosphorus Compounds, Vol. 2, Wiley-Interscience, 1992, Ch. 8, and Refs. therein; J.R. Black and W. Levason, J. Chem. Soc., Dalton Trans., (1994) 3225.
9. G. Pilloni, R. Graziani, B. Longato and B. Corain, Inorg. Chim. Acta, 190 (1991) 165.
10. G. Pilloni, B. Longato and B. Corain, J. Organomet. Chem., 420 (1991) 57.
11. J.J. Bishop, A. Davison, M.L. Katcher, D.W. Lichtenberg, R.E. Merrill and J.C. Smart, J. Organomet. Chem., 27 (1971) 241.
12. S. Ninoreille, R. Broussier, R. Amardeil, M.M. Kubicki and B. Gautheron, Bull. Soc. Chim. Fr., 132 (1995) 128.
13. (a) G.M. Sheldrick, SHELXTL/PC, Version 5.03, Siemens Analytical X-ray Instruments Inc., Madison, WI, 1994;
14. (b) G.M. Sheldrick, SHELXL-93, program for the refinement of crystal structures, University of Göttingen, Germany, 1993.
15. C.K. Johnson, ORTEP, Rep. ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
16. F.H. Allen, J.E. Davies, J.J. Galloy, O. Johnson, O. Kennard, C.F. Macrae, E.M. Mitchell, G.F. Mitchell, J.M. Smith and D.G. Watson, J. Chem. Inf. Comput. Sci., 31 (1991) 187; Cambridge Structural Database (CSD) System, Version 5.12, Oct. 1996.
17. F.H. Allen, J.E. Davies, J.J. Galloy, O. Johnson, O. Kennard, C.F. Macrae, E.M. Mitchell, G.F. Mitchell, J.M. Smith and D.G. Watson, J. Chem. Inf. Comput. Sci., 31 (1991) 187; Cambridge Structural Database (CSD) System, Version 5.12, Oct. 1996.
18. U. Casellato, R. Graziani and G. Pilloni, J. Crystallogr. Spectrosc. Res., 23 (1993) 571.
19. K.-S. Gan and T.S.A. Hor, in A. Togni and T. Hayashi (eds.), Ferrocenes: Homogeneous Catalysis, Organic Synthesis, Materials Science, VCH, Weinheim, 1995, Ch. 1, and Refs. therein.
20. D.H. Brown, R.J. Cross and R. Keat, J. Chem. Soc., Dalton Trans., (1980) 871.
21. (a) J. Kaiser, R. Richter and J. Sieler, Acta Crystallogr., Sect. B, 31 (1975) 260;
22. (b) M. Bonamico and G. Dessy, J. Chem. Soc. A, (1971) 264.
23. J. Podlaha, P. Štepnička , J. Ludvík and I. Císařová, Organometallics, 15 (1996) 543.