The range in static stereochemistry of the cation distortion isomers of the [Cu(chelate)2Cl]+ cation, where chelate=bipy, phen or bipyam. The low temperature crystal structure (150 K) of [Cu(bipy)2Cl][PF6]·H2O and [Cu(phen)2Cl][BPh4]

Polyhedron

Volumn 18, Issue 5, 1999, Pages 611-615

  Brophy, Mark ^a   Murphy, Gillian ^a   O'Sullivan, Cathal ^a   Hathaway, Brian ^a   Murphy, Brian ^b  

^a UNIVERSITY COLLEGE CORK   (Ireland)

^b CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

Cation distortion isomer; Low temperature; Static copper(II) stereochemistries

Indexed keywords

CHELATION; COPPER COMPOUNDS; CRYSTAL STRUCTURE; ISOMERS; PLANTS (BOTANY); STEREOSELECTIVITY; TEMPERATURE;

CATION DISTORTION ISOMER; LOW TEMPERATURE CRYSTAL STRUCTURE; LOWS-TEMPERATURES; STATIC COPPER(II) STEREOCHEMISTRY; TRIGONAL BIPYRAMIDAL;

POSITIVE IONS;

EID: 0000998352     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(98)00212-5     Document Type: Article

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