Different modes of reaction of lithium phosphides with Cp *M(NO)(X)Cl complexes of molybdenum and tungsten

Organometallics

Volumn 16, Issue 2, 1997, Pages 190-196

  Legzdins, Peter ^a   Ross, Kevin J ^a   Sayers, Stephen F ^a   Rettig, Steven J ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000997319     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960608+     Document Type: Article

References (44)

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23. 1H NMR spectra were recorded. In all cases the spectra indicated the presence of a plethora of products as judged by the numerous signals in the Cp* region. The reactions were also effected in MeCN as the reaction solvent with similar results.
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29. 2 with LiPPhH but is isolable only in an impure form and in very low yield.
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37. Preliminary details of this structure have been communicated previously; see ref 24.
38. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
39. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
40. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
41. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
42. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
43. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]
44. For examples of similar three-coordinate lithium centers see: (a) Hvoslef, J.; Hope, H.; Murray, B. D.; Power, P. P. J. Chem. Soc., Chem. Commun. 1983, 1438. (b) Huffman, J. C.; Geerts, R. L.; Caulton, K. G. J. Cryst. Spectrosc. 1984, 14, 541. (c) Becker, G.; Hartmann, H.-M.; Munch, A.; Riffel, H. Z. Anorg. Allg. Chem. 1985, 29, 530. (d) Engelhardt, L. M.; Harrowfield, J. M.; Lappert, M. F.; MacKinnon, I. A.; Newton, B. H.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 846. (e) Weese, K. H.; Bartlett, R. A.; Murray, B. D.; Olmstead, M. M.; Power, P. P. Inorg. Chem. 1987, 26, 2409. (f) Askham, F. R.; Carroll, K. M.; Alexander, S. J.; Rheingold, A. L.; Haggerty, B. S. Organometallics 1993, 12, 4810. [Obtained from the Cambridge Structural Data Base: Allen, F. H.; Kennard, O. Chem. Design Automation News 1993, 8, 31.]