Synthesis and characterization of bis(arenethiolato)magnesium complexes with intramolecular coordination. x-ray structure of [Mg{S(C6H4-2-CH2NMe2)} 2]2

Inorganic Chemistry

Volumn 35, Issue 11, 1996, Pages 3436-3439

  Janssen, Maurits D ^a   Van Rijst, Remco Der ^a   Spek, Anthony L ^b   Grove, David M ^a   Van Koten, Gerard ^a  

^a UTRECHT UNIVERSITY   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000993029     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951288+     Document Type: Article

References (34)

1. Grignard, V. C. R. Hebd. Seances Acad. Sci. 1900, 130, 1322.
2. Markies, P. R.; Akkerman, O. S.; Bickelhaupt, F.; Smeets, W. J. J.; Spek, A. L. Adv. Organomet. Chem. 1991, 32, 147-226
3. (a) Lambert, F.; Knotter, D. M.; Janssen, M. D.; van Klaveren, M.; Boersma, J.; van Koten, G. Tetrahedron: Asymmetry 1991, 2, 1097-1100.
4. (b) van Klaveren, M.; Lambert, F.; Eijkelkamp, J. F. M.; Grove, D. M.; van Koten, G. Tetrahedron Lett. 1994, 35, 6135-6138.
5. (c) Haubrich, A.; van Klaveren, M.; van Koten, G.; Handke, G.; Krause, N. J. Org. Chem. 1993, 58, 5849-5852.
6. (d) van Klaveren, M.; Persson, E. S. M.: Grove, D. M.: Bäckvall, J. E.; van Koten, G. Tetrahedron Lett. 1994, 35, 5931-5934.
7. (e) Persson, E. S. M.; van Klaveren, M.; Bäckvall, J. E.; van Koten, G. Chem. Eur. J. 1995, 1, 351-359.
8. (a) Knotter, D. M.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 1990, 112, 5895-5896.
9. (b) Knotter, D. M.; Grove, D. M.; Smeets, W. J. J.: Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 1992, 114, 3400-3410.
10. + cations.
11. (a) Markies, P R.; Altink, R. M.; Villena, A.; Akkerman, O. S.; Bickelhaupt, F. J. Organomet. Chem. 1991, 402, 289-312.
12. (b) Villena, A. Quantitative Aspects of Intramolecular Coordination in Organomagnesium Compounds. Thesis; Vrije Universiteit, Amsterdam, 1986.
13. (a) Jastrzebski, J. T. B. H.; van Koten, G. Inorg. Synth. 1989, 26, 150-155.
14. (b) Jastrzebski, J. T. B. H.; van Koten, G.; Konijn, M.; Stam, C. H. J. Am. Chem. Soc. 1982, 104, 5490-5492.
15. Knotter, D. M.; van Maaners, H. L.; Grove, D. M.: Spek, A. L.; van Koten, G. Inorg. Chem. 1991, 30, 3309-3317.
16. Knotter, D. M.; Janssen, M. D.; Grove, D M.; Smeets, W. J. J.; Horn, E.; Spek, A. L.; van Koten, G. Inorg. Chem. 1991, 30, 4361-4366.
17. de Boer, J. L.; Duisenberg, A. J. M. Acta Crystallogr. 1984, A40, C410.
18. Spek, A. L. J. Appl. Crystallogr 1988, 21, 578-579.
19. Walker, N.; Stuart, D. Acta Crystallogr. 1983. A39, 158-166.
20. Spek, A. L. Acta Crystallogr. 1990, A46, C34.
21. Sheldrick, G. M. SHELXS86: Program for crystal structure determination; University of Gottingen: Gottingen, Germany, 1986.
22. Sheldrick, G. M. SHELXL93: Program for crystal structure refinement: University of Göttingen: Göttingen, Germany, 1993.
23. Wilson, A. J. C., ed. International Tables for Crystallography. Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992: Vol. C.
24. Houben-Weyl. Methoden der Organischen Chemie, 4th ed.; Georg Thieme Verlag: Stuttgart, Germany, 1973; Vol. 13/2a.
25. Holmes, R. R. Prog. Inorg. Chem. 1984, 32, 119-235 and references cited therein.
26. Ruhlandt-Senge, K. Inorg. Chem. 1995, 34, 3499-3504.
27. Pappas, J. A J. Am. Chem. Soc. 1978, 100, 6023-6027.
28. Bochmann, M.; Bwembya, G.: Grimer, R.; Lu, J.: Webb, K. J.: Williamson, D. J.; Hursthouse, M. B ; Mazid, M. Inorg. Chem. 1993, 32, 532-537.
29. (a) Power, P. P.; Shoner, S. C. Angew. Chem., Int. Ed. Engl. 1991, 30, 330-332.
30. (b) MacDonnell, F. M.; Ruhlandt-Senee, K.; Ellison, J. J.: Holm, R. H.; Power, P. P. Inorg. Chem. 1995, 34, 1815-1822.
31. Ruhlandt-Senge, K.; Power, P. P. Bull. Soc. Chim. Fr. 1992, 129, 594-598.
32. Brandts, J. A. M.; Hogerheide, M. P.; Janssen, M. D.; Spek, A. L.; van Koten, G. Unpublished results.
33. c = coalescence temperature (K), Δν = chemical shift difference (Hz), and the other symbols have their usual meaning.
34. Janssen, M. D.; Rijnberg, E.; de Wolf, C. A.; Hogerheide, M. P.; Kruis, D., Kooijman, H.; Spek, A. L.; Grove, D M.; van Koten, G. Unpublished results.