Preparation, Structure, and Properties of Bis(μ-oxo)dirhenium(III,IV) and -dirhenium(IV) Complexes of Tris(2-pyridylmethyl)amine and Its (6-Methyl-2-pyridyl)methyl Derivatives

Inorganic Chemistry

Volumn 35, Issue 24, 1996, Pages 7082-7088

  Sugimoto, Hideki ^a   Kamei, Masaki ^a   Umakoshi, Keisuke ^a   Sasaki, Yoichi ^a   Suzuki, Masatatsu ^b  

^a HOKKAIDO UNIVERSITY   (Japan)

^b KANAZAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000992289     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960445h     Document Type: Article

References (70)

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63. 3CN were collected with graphite-monochromated Mo Ka radiation on a MacScience MXC18 diffractometer at 163 K. The triclinic space group P1 was observed with a = 12.191-(5) Å, b = 22.373(6) Å, c = 12.000(4) Å, α = 100.29(2)°, β= 99.06(3)°, and γ = 78.28(3)°. The structure was solved and refined to a conventional R factor of 0.12. The standard deviations of bond lengths and angles are large, but the general feature of the structure are clear enough to recognize the isomer.
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67. Converted the literature value reported with reference to SCE.
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70. 2, but this case also suffered from the contamination of some unknown decomposition products. Nevertheless, we obtained evidence for the existence of at least two geometrical isomers as typically seen in the 6H of the py ring which shows splitting.