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A core-level excitation whose absorption coefficient is small compared to the total absorption, as is the case for the O (Formula presented) edge, leads to a very poor signal-to-background ratio in TEY, but has the distinct advantage that self-absorption effects in the FY mode remain small. The situation is just reversed in the case of the relatively strong Cu (Formula presented) absorption.
-
A core-level excitation whose absorption coefficient is small compared to the total absorption, as is the case for the O (Formula presented) edge, leads to a very poor signal-to-background ratio in TEY, but has the distinct advantage that self-absorption effects in the FY mode remain small. The situation is just reversed in the case of the relatively strong Cu (Formula presented) absorption.
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85037916873
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The spectra for (Formula presented) were obtained by extrapolation from measurements at grazing incidence (Formula presented) off the sample surface normal).
-
The spectra for (Formula presented) were obtained by extrapolation from measurements at grazing incidence (Formula presented) off the sample surface normal).
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14
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0344845267
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For an overview, see J. Fink, N. Nücker, E. Pellegrin, H. Romberg, M. Alexander, and M. Knupfer, J. Electron Spectrosc. Relat. Phenom. 66, 395 (1994).
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Transitions into unoccupied Cu (Formula presented) orbitals are also allowed, but show a reduced transition probability by a factor of 20 compared to Cu (Formula presented) final states: B.K. Teo and P.A. Lee, J. Am. Chem. Soc. 101, 2815 (1979).
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85037880988
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In the evaluation of the spectral weight, different matrix elements for transitions into Cu (Formula presented) and Cu (Formula presented) states were taken into account.
-
In the evaluation of the spectral weight, different matrix elements for transitions into Cu (Formula presented) and Cu (Formula presented) states were taken into account.
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19
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