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Volumn 30, Issue 2, 1989, Pages 251-252

Selective and sequential reduction of nitroaromatics by montmorillonitesilylaminepalladium(II) complex

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000981050 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)95173-6 Document Type: Article

Times cited : (36)

References (7)

1
- 0004209530
- Academic Press, New York
- (1985) Hydrogenation Methods
- Raylander¹

2
- 0010516738
- and references therein
- (1988) Tetrahedron Lett. , vol.29 , pp. 635
- Huber¹ Andermann² Leclerc³

3
- 0000546098
- and references therein
- (1980) J.Org.Chem. , vol.45 , pp. 4992
- Terpko¹ Heck²

6
- 84918610645
- Catalyst synthesis is as follows: H-Montmorillonite(10.0 g),which was prepared from natural montmorillonite K10(Fluka)by treating first with saturated NaCl followed by 0.1 N HCl, on reaction with 3-aminopropyltriethoxysilane (1.55g, 7.0 mmol) in dry toluene under reflux for 48 hrs to afford montmorillonite interlamellar 3-aminopropyltriethoxysilane. This on complexation with bis (benzonitrile)palladium(II)chloride (Aldrich) (2.0 mmol for 1.0 g ligand) in dry benzene gave the catalyst (1). For further details : Y.V. Subba Rao, K. Mukkanti and B.M. Choudary, J.Mol.Cat. (In press)

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