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5 The authors have traced it back to a more general, albeit empirical, approach due to Porter who assumed, as early as in 1920, a special form for the molar excess free enthalpy, symmetric for both components. No assumptions were made about the excess entropy. It has been suggested in ref 5 to use the expression "symmetrical mixture" instead of "regular solution". As regards the terminology, we feel that the mean-field approximation is still more appropriate, as it appears all throughout the statistical thermodynamics.
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