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Volumn 12, Issue 20, 1996, Pages 4672-4680

On the distribution of surfactants among mixed micelles

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000972214     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la960107t     Document Type: Article
Times cited : (40)

References (30)
  • 2
    • 0000005168 scopus 로고
    • Mittal, K. L., Ed.; Plenum Press: New York
    • Rubingh, D. N. In Solution Chemistry of Surfactants; Mittal, K. L., Ed.; Plenum Press: New York, 1979; Vol. 1, p 337.
    • (1979) Solution Chemistry of Surfactants , vol.1 , pp. 337
    • Rubingh, D.N.1
  • 6
  • 7
    • 5244367208 scopus 로고    scopus 로고
    • note
    • The term regular solution was actually introduced by Hildebrand in 1929 to distinguish mixtures with experimentally determined zero excess entropy. Guggenheim defined a model for the so-called strictly regular solution, which could then be analyzed by the methods of statistical thermodynamics.
  • 8
    • 5244340751 scopus 로고    scopus 로고
    • note
    • 5 The authors have traced it back to a more general, albeit empirical, approach due to Porter who assumed, as early as in 1920, a special form for the molar excess free enthalpy, symmetric for both components. No assumptions were made about the excess entropy. It has been suggested in ref 5 to use the expression "symmetrical mixture" instead of "regular solution". As regards the terminology, we feel that the mean-field approximation is still more appropriate, as it appears all throughout the statistical thermodynamics.
  • 29
    • 85088619322 scopus 로고    scopus 로고
    • note
    • N configurations are involved.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.