Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide

Journal of Organometallic Chemistry

Volumn 509, Issue 1, 1996, Pages 101-104

  Chin, Choon Hong ^a   Hor, T S Andy ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Carbon monoxide; Carbonyl sulfide; Desulfurization; Platinum; Reductive carbonylation; Sulfide

Indexed keywords

EID: 0000964477     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328x(95)05783-l     Document Type: Article

References (49)

1. (a) R. Ugo, G. La Monica, S. Cenini, A. Segre and F. Conti, J. Chem. Soc. A, (1971) 522
2. (b) B.H. Aw, K.K. Looh, H.S.O. Chan, K.L. Tan and T.S.A. Hor, J. Chem. Soc., Dalton Trans., (1994) 3177
3. (c) T.S.A. Hor and A.L.C. Tan, Inorg. Chim. Acta. 142 (1988) 173
4. (d) T.S.A. Hor, Bull. Sing. Natl. Inst. Chem., 13 (1985) 3
5. (e) C. Battistoni, G. Mattogno and D.M.P. Mingos. Inorg. Chim. Acta. 86 (1984) L39.
6. C.E. Briant, C.J. Gardner, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1984) 2645; R.R. Gukathasan, R.H. Morris and A. Walker, Can J. Chem., 61 (1983) 2490.
7. C.E. Briant, C.J. Gardner, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1984) 2645; R.R. Gukathasan, R.H. Morris and A. Walker, Can J. Chem., 61 (1983) 2490.
8. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
9. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
10. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
11. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
12. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
13. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
14. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
15. C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Chem. Soc., Chem. Commun., (1983) 1118; C.E. Briant, T.S.A. Hor, N.D. Howells and D.M.P. Mingos, J. Organomet. Chem., 256 (1983) C15; C.E. Briant, D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc, Dalton Trans., (1985) 851; D.I. Gilmour, M.A. Luke and D.M.P. Mingos, J. Chem. Soc., Dalton Trans., (1987) 335; M. Zhou, Y. Xu, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Horm Inorg. Chem., 32 (1993) 1875; M. Zhou, Y. Xu, C-F. Lam, L.-L. Koh, K.F. Mok, P.-H. Leung and T.S.A. Hor. Inorg. Chem., 32 (1993) 4660; M. Zhou, Y. Xu, C-F. Lam, P-H. Leung, L.-L. Koh, K.F. Mok and T.S.A. Hor, Inorg. Chem., 33 (1994) 1572; W. Bos, J.J. Bour, P.P.J. Sehlebos, P. Hageman, W.P. Bosman, J.M.M. Smits, J.A.C. van Wietmarschen and P.T. Beurskens, Inorg. Chim. Acta, 119 (1986) 141.
16. M. Zhou, C.F. Lam, K.F. Mok, P.-H. Leung and T.S.A. Hor, J. Organomet. Chem., 476 (1994) C32; T.S.A. Hor, D. Phil. Thesis, University of Oxford, 1983.
17. M. Zhou, C.F. Lam, K.F. Mok, P.-H. Leung and T.S.A. Hor, J. Organomet. Chem., 476 (1994) C32; T.S.A. Hor, D. Phil. Thesis, University of Oxford, 1983.
18. J. Chatt and D.M.P. Mingos, J. Chem. Soc. A. (1970) 1243.
19. (a) M.C. Baird and G. Wilkinson, J. Chem. Soc. A. (1967) 865
20. (b) A.C. Skapski and P.G.H. Troughton, J. Chem. Soc. A, (1969) 2772
21. (c) C.T. Hunt, G.B. Matson and A.L. Balch, Inorg. Chem., 20 (1981) 2270
22. (d) M.F. Hallam, M.A. Luke, D.M.P. Mingos and I.D. Williams, J. Organomet. Chem., 325 (1987) 271.
23. D.G. Evans, M.F. Hallam, D.M.P. Mingos and R.W.M. Wardle, J. Chem. Soc., Dalton Trans., (1987) 1889.
24. R.A. Paciello, Organometallics, 12 (1993) 565; F. Calderazzo and G. Pampaloni, J. Organomet. Chem., 250 (1983) C33; F. Calderazzo and R. Poli, Gazz. Chim. Ital., 115 (1985) 573; S. Bucknor, F.A. Cotton, L.R. Falvello, A.H. Reid, Jr., and C.D. Schmulbach, Inorg. Chem., 25 (1986) 1021; F.A. Cotton, D.J. Darensbourg and B.W.S. Kolthammer, J. Organomet. Chem., 217 (1981) C14.
25. R.A. Paciello, Organometallics, 12 (1993) 565; F. Calderazzo and G. Pampaloni, J. Organomet. Chem., 250 (1983) C33; F. Calderazzo and R. Poli, Gazz. Chim. Ital., 115 (1985) 573; S. Bucknor, F.A. Cotton, L.R. Falvello, A.H. Reid, Jr., and C.D. Schmulbach, Inorg. Chem., 25 (1986) 1021; F.A. Cotton, D.J. Darensbourg and B.W.S. Kolthammer, J. Organomet. Chem., 217 (1981) C14.
26. R.A. Paciello, Organometallics, 12 (1993) 565; F. Calderazzo and G. Pampaloni, J. Organomet. Chem., 250 (1983) C33; F. Calderazzo and R. Poli, Gazz. Chim. Ital., 115 (1985) 573; S. Bucknor, F.A. Cotton, L.R. Falvello, A.H. Reid, Jr., and C.D. Schmulbach, Inorg. Chem., 25 (1986) 1021; F.A. Cotton, D.J. Darensbourg and B.W.S. Kolthammer, J. Organomet. Chem., 217 (1981) C14.
27. R.A. Paciello, Organometallics, 12 (1993) 565; F. Calderazzo and G. Pampaloni, J. Organomet. Chem., 250 (1983) C33; F. Calderazzo and R. Poli, Gazz. Chim. Ital., 115 (1985) 573; S. Bucknor, F.A. Cotton, L.R. Falvello, A.H. Reid, Jr., and C.D. Schmulbach, Inorg. Chem., 25 (1986) 1021; F.A. Cotton, D.J. Darensbourg and B.W.S. Kolthammer, J. Organomet. Chem., 217 (1981) C14.
28. R.A. Paciello, Organometallics, 12 (1993) 565; F. Calderazzo and G. Pampaloni, J. Organomet. Chem., 250 (1983) C33; F. Calderazzo and R. Poli, Gazz. Chim. Ital., 115 (1985) 573; S. Bucknor, F.A. Cotton, L.R. Falvello, A.H. Reid, Jr., and C.D. Schmulbach, Inorg. Chem., 25 (1986) 1021; F.A. Cotton, D.J. Darensbourg and B.W.S. Kolthammer, J. Organomet. Chem., 217 (1981) C14.
29. 2 Calc.: C, 54.1; H, 4.4; P, 6.9; Pt, 28.8; S, 4.7%.
30. 2 has been discussed in detail together with the identification of the products (see [4]).
31. 2S Calc.: C, 47.5; H, 3.2; P, 5.9; Pt, 37.2%.
32. 2S Calc.: C, 52.6; H, 3.7; S, 2.6; Pt, 31.1%.
33. 4.
34. 2S Calc.: C, 57.4; H, 4.2; P, 8.2; Pt, 25.9; S, 2.1%.
35. Complexes 2 and 6-8 were isolated but 3-5 were detected as intermediates in the reaction mixtures, The IR spectra of these species were recorded under atmospheric pressure in CO (2-5) or argon (6-8) atmosphere. Solutions containing 2-5 were drained out from the autoclave liner (under CO) and their spectra recorded immediately. No strenuous effort was made to detect the transient species which exist only under high pressure conditions. Spectral assignments of the unisolable intermediates are tentative.
36. 3 or other sulfur compounds as byproducts further supported this claim.
37. T.R. Gaffney and J. A. Ibers, Inorg. Chem., 21 (1982) 2860; J.A. Ibers, Chem. Soc. Rev., 11 (1982) 57.
38. T.R. Gaffney and J. A. Ibers, Inorg. Chem., 21 (1982) 2860; J.A. Ibers, Chem. Soc. Rev., 11 (1982) 57.
39. J.C. Bryan, S.J. Geib. A.L. Rheingold and J.M. Mayer, J. Am. Chem. Soc., 109 (1987) 2826: N.S. Nametkiu, B.I. Kolobkov, V.D. Tyurin, A.N. Muratov, A.I. Nekhaev, M. Mavlonov, A.Y. Sideridu, G.G. Aleksandrov, A.V. Lebedev, M.T. Tashev and H.B. Dustov, J. Organomet, Chem., 276 (1984) 393: C. Glidewell, J. Organomet. Chem., 295 (1985) 73.
40. J.C. Bryan, S.J. Geib. A.L. Rheingold and J.M. Mayer, J. Am. Chem. Soc., 109 (1987) 2826: N.S. Nametkiu, B.I. Kolobkov, V.D. Tyurin, A.N. Muratov, A.I. Nekhaev, M. Mavlonov, A.Y. Sideridu, G.G. Aleksandrov, A.V. Lebedev, M.T. Tashev and H.B. Dustov, J. Organomet, Chem., 276 (1984) 393: C. Glidewell, J. Organomet. Chem., 295 (1985) 73.
41. J.C. Bryan, S.J. Geib. A.L. Rheingold and J.M. Mayer, J. Am. Chem. Soc., 109 (1987) 2826: N.S. Nametkiu, B.I. Kolobkov, V.D. Tyurin, A.N. Muratov, A.I. Nekhaev, M. Mavlonov, A.Y. Sideridu, G.G. Aleksandrov, A.V. Lebedev, M.T. Tashev and H.B. Dustov, J. Organomet, Chem., 276 (1984) 393: C. Glidewell, J. Organomet. Chem., 295 (1985) 73.
42. P.-F. Fu, M.A. Khan and K.M. Nicholas, Organometallics, 12 (1993) 3790.
43. C.S. Browning, D.H. Farrar, R.R. Gukathasan and S.A. Morris, Organometallics, 4 (1985) 1750.
44. T.R. Gaffney and J.A. Ibers, Inorg. Chem., 21 (1982) 2854.
45. A. Müller and E. Diemann, in G. Wilkinson, R.D. Gillard and J.A. McCleverty (eds.), Comprehensive Coordination Chemistry, Vol. 2, Pergamon, Oxford, 1987, Chapter 16.1, p. 538.
46. Complex 1 readily dissolves in chlorinated solvents but decomposition rapidly follows.
47. B. Chaudret, B. Delavaux and R. Poilblanc, Coord. Chem. Rev., 86 (1988) 191; R.J. Puddephatt, Chem. Soc. Rev., 12 (1983) 99.
48. B. Chaudret, B. Delavaux and R. Poilblanc, Coord. Chem. Rev., 86 (1988) 191; R.J. Puddephatt, Chem. Soc. Rev., 12 (1983) 99.
49. G.K. Anderson, Adv. Organomet. Chem., 35 (1993) 1.