Influence of the sulfinyl group on the chemoselectivity and π-facial selectivity of diels-alder reactions of (S)-2-(p Tolylsulfinyl)-1,4-benzoquinone

Journal of Organic Chemistry

Volumn 61, Issue 2, 1996, Pages 503-509

  Carreno, M Carmen ^a   Garcia Ruano, José L ^a   Toledo, Miguel A ^a   Urbano, Antonio ^a   Remor, Cynthia Z ^b   Stefani, Valter ^b   Fischer, Jean ^c  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

^b FEDERAL UNIVERSITY OF RIO GRANDE DO SUL   (Brazil)

^c UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000961938     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo951438y     Document Type: Article

References (31)

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18. The authors have deposited atomic coordinates for 4b with the Cambridge Crystallographic Data Centre. The coordinates can be obtained, on request, from the Director, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK.
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26. 2, a mixture of compound 16 and that resulting from the 1,4-addition of the diene to the activated double bond was formed. After flash chromatography, 16 could be isolated and characterized (see ref 3 for physical and spectra] data of 16).
27. 2 had the same configuration in its stereogenic centers that adduct 4b, as was demonstrated by X-ray diffraction: unpublished results.
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