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2 bending vibrations are expected to be observed, are not shown beause of a high noise level in this region, which is caused by mechanical vibrations emitted by the cryostat.
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-1). We repeated the measurement at least three times, confirming the frequency shift. So we believe that the shift cannot be ascribed to an experimental artifact but reflects a real situation. The same can be applied to frequency shifts of a few wavenumbers observed for IR bands discussed below.
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