Synthesis, Characterization, and Solid-State Structure of a New Hexachelating Ligand and Its Complex with Gallium(III)

Inorganic Chemistry

Volumn 28, Issue 8, 1989, Pages 1504-1506

  Moore, Dennis A ^a   Fanwick, Phillip E ^b   Welch, Michael J ^a  

^a WASHINGTON UNIVERSITY SCHOOL OF MEDICINE   (United States)

^b PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000959033     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00307a016     Document Type: Article

References (8)

1. Bulman, R. A. Structure and Bonding; Springer-Verlag: Berlin, 1987; Vol. 67.
2. Mathias, C. J.; Sun, Y.; Welch, M. J.; Green, M. A.; Thomas, J. A.; Wade, K. R.; Martell, A. E. Nucl. Med. Biol. 1988, 15, 69.
3. Metal complexes that cross the blood-brain barrier (e.g. Tc-PnAO) are typically neutral and very lipophilic: Holm, S.; Andersen, A. R.; Vorstrup, S.; Lassen, N. A.; Paulson, O. B.; Holmes, R. A. J. Nucl. Med. 1985, 26, 1129.
4. White, D. W.; Karcher, B. A.; Jacobson, R. A.; Verkade, J. G. J. Am. Chem. Soc. 1979, 101, 4921.
5. Walker, N.; Stuart, D. Acta Crystallogr., Sect. A 1983, A39, 158.
6. Julia, M. Bull. Soc. Chim. Fr. 1955, 850.
7. The solubility properties of this complex are in stark contrast with those of a similar complex, Ga[(5-MeOsal)3tame]: Green, M. A.; Welch, M. J. J. Am. Chem. Soc. 1984, 106, 3689.
8. Schuster, P.; Zundel, G.; Sandorfy, C. Hydrogen Bonding; North-Holland Publishing Co.: Amsterdam, 1976; distributed in the U. S. A. by Elsevier Publishing Co., Inc., 52 Vanderbilt Ave., New York 10017.