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85087225889
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13C NMR data are available as Supporting Information for 2a, 2b, (±)-3a, and (±)-3b
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13C NMR data are available as Supporting Information for 2a, 2b, (±)-3a, and (±)-3b.
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13
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17
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0041690056
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note
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1H NMR spectrum for (±)-3a is more compelling: 6 phenyl proton resonances are observed with all but the 4 o-protons coincidentally overlapping between 7.56 and 7.67 ppm. The chemical shift differences between the individual resonances of the m- and p-protons is small. By contrast, the 4 o-protons, 2 of which are closest to the fullerenic methines in (±)-3a, exist as a pair of quasi-doublets centered at 8.29 and 8.68 ppm (Δδ = 0.39 ppm).
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19
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