Quadruply Bonded Complexes Containing Bridging Acetate and μ3-Phosphine Ligands. Synthesis and Structural Characterization of the Molybdenum Complexes (1) and (2) (see abstract)

Inorganic Chemistry

Volumn 35, Issue 10, 1996, Pages 2930-2936

  Lee, Chang Tai ^a   Chiang, Shih Fu ^a   Chen, Chun Ting ^a   Chen, Jhy Der ^a   Hslao, Chwan Deng ^b  

^a CHUNG YUAN CHRISTIAN UNIVERSITY   (Taiwan)

^b INSTITUTE OF MOLECULAR BIOLOGY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000953880     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951187b     Document Type: Article

References (23)

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12. w = 0.1280. Each asymmetric unit contains two independent molecules. Selected bond distances (A) and bond angles (deg): Mo(1)-Mo(2) = 2.121-(3), Mo(3)-Mo(4) = 2.134(3), Mo(3) - Cl(4) = 2.410(9), Mo(3)-P(5) = 2.583(8), Mo(3)-P(7) = 2.501(9), Mo(3)-O(3) = 2.11(2), Mo(4)-Cl(5) = 2.363(9), Mo(4)-Cl(6) = 2.403(7), Mo(4)-P(6) = 2.521(8), Mo(4) - O(4) = 2.12(2); Mo(4)-Mo(3)-Cl(4) = 108.9(2), Mo(4)-Mo(3)-P(5) = 104.5(2), Mo(4)-Mo(3)-P(7) = 99.8(2), Mo-(4)-Mo(3)-O(3) = 91.7(4), Cl(4)-Mo(3)-P(5) = 96.9(3), Cl(4)Mo(3)-P(7) = 151.1(3), Cl(4)-Mo(3)-0(3) = 89.2(5), P(5)-Mo(3)-P(7) = 78.0(3), P(5)-Mo(3)-O(3) = 159.6(5), P(7)-Mo(3)-O(3) = 87.3(5), Mo(3)-Mo(4)-Cl(5) = 106.8(2), Mo(3)-Mo(4)-Cl(6) = 110.7(2), Mo(3)-Mo(4)-P(6) = 105.6(2), Mo(3)-Mo(4)-O(4) = 92.0(4), Cl(5)-Mo(4)-CI(6) = 142.4(3), Cl(5)-Mo(4)-P(6) = 85.6(3), Cl(5)-Mo(4)-O(4) = 87.0(6), Cl(6)-Mo(4)-P(6) = 83.6-(3), Cl(6)-Mo(4)-O(4) = 92.6(6). P(6)-Mo(4)-O(4) = 162.3(5). Complete tables of crystal data, anisotropic thermal parameters, bond distances, and bond angles are provided as Supporting Information.
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