The question of aromaticity in the 1-lithio-1-methyl-1-silafluorenide anion. Evidence for a localized silyl anion

Organometallics

Volumn 15, Issue 8, 1996, Pages 2179-2181

  Hong, Jang Hwan ^a   Boudjouk, Philip ^a   Stoenescu, Ioana ^a  

^a NORTH DAKOTA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000953870     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9509195     Document Type: Article

References (18)

1. Boudjouk, P.; Hong, J.-H. The Sendai International Symposium on the Frontiers of Organosilicon Symposium, Sendai, Japan, Nov 4-6, 1994; Abstract IL6.
2. Hong, J.-H.; Boudjouk, P. J. Am. Chem. Soc. 1993, 115, 5883.
3. Goldfuss, B.; Schleyer, P. v. R. Organometallics 1995, 14, 1555.
4. March, J. Advanced Organic Chemistry, 4th ed.; John Wiley & Sons: New York, 1992; pp 45-46.
5. 2 has been used as an intermediate: (a) Gilman, H.; Gorsich, R. D. J. Am. Chem. Soc. 1958, 80, 3243. (b) Ishikawa, M.; Tabohashi, T.; Ohashi, H.; Kumada, M.; Iyoda, J. Organometallics 1983, 2, 351.
6. 2 has been used as an intermediate: (a) Gilman, H.; Gorsich, R. D. J. Am. Chem. Soc. 1958, 80, 3243. (b) Ishikawa, M.; Tabohashi, T.; Ohashi, H.; Kumada, M.; Iyoda, J. Organometallics 1983, 2, 351.
7. (a) Olah, G. A.; Hunadi, R. J. J. Am. Chem. Soc. 1980, 102, 6989.
8. (b) Edlund, U.; Lejon, T.; Venkatachalam, T. K.; Buncel, E. J. Am. Chem. Soc. 1985, 107, 6408.
9. (c) Edlund, U.; Lejon, T.; Pyykkö, P.; Venkatachalam, T. K.; Buncel, E. J. Am. Chem. Soc. 1987, 109, 5982.
10. Fürstner, A.; Weidmann, H. J. Organomet. Chem. 1988, 354, 15.
11. (a) Buncel, E.; Venkatachalam, T. K.; Eliasson, B. J.; Edlund, U. J. Am. Chem. Soc. 1985, 107, 303.
12. (b) Buncel, E.; Venkatachalam, T. K.; Edlund, U.; Eliasson, B. J. J. Chem. Soc. Chem. Commun. 1984, 1476.
13. Dufour, P.; Dubac, J.; Dartiguenave, M.; Dartiguenave, Y. Organometallics 1990, 9, 3001.
14. Freeman, W. P.; Tilley, T. D.; Arnold, F. P.; Rheingold, A. L.; Gantzel, P. K. Angew. Chem., Int. Ed. Engl. 1995, 34, 1887.
15. Stothers, J. B. Carbon-13 NMR Spectroscopy; Academic Press: New York, 1972; Chapter 3, pp 77-91.
16. For reviews of the effects of ultrasonic waves on heterogeneous reactions see: (a) Boudjouk, P. In High Energy Processes in Organometallic Chemistry; Suslick, K. S., Ed.; ACS Symposium Series 333; American Chemical Society: Washington, DC, 1987; Chapter 13. (b) Boudjouk, P. In Ultrasound: Chemical, Physical and Biological Effects; Suslick, K. S., Ed.; Verlag Chemie: Deerfield Beach, FL, 1988; Chapter 5.
17. For reviews of the effects of ultrasonic waves on heterogeneous reactions see: (a) Boudjouk, P. In High Energy Processes in Organometallic Chemistry; Suslick, K. S., Ed.; ACS Symposium Series 333; American Chemical Society: Washington, DC, 1987; Chapter 13. (b) Boudjouk, P. In Ultrasound: Chemical, Physical and Biological Effects; Suslick, K. S., Ed.; Verlag Chemie: Deerfield Beach, FL, 1988; Chapter 5.
18. Ishikawa, M.; Tabohashi, T.; Sugisawa, H.; Nishimura, K.; Kumada, M. J. Organomet. Chem. 1983, 250, 109.