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Because of our inability to accurately measure the film thickness in situ, we neglected the contribution of thickness changes to the film stress. A precedent for our approach is found in tensile stress measurements of bulk materials, which are often made with the assumption of a constant cross-sectional area (15). We also ignored the possibility of any spatial gradients in IT within the monolayer. Measurements of π were consistently taken from the center of the trough with the compression direction normal to the face of the Wilhelmy plate to ensure reproducibility.
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o, original length) (15). For such tensile deformation studies, it is necessary to maintain a constant geometry between experiments for the purposes of accurate comparison. Because we draw from the literature developed from the mechanical response of bulk materials to tensile deformation, we use an engineering strain and strain rate. To ensure the validity of comparison between experiments, we spread approximately equal amounts of amphiphilic material at the air-water interface for each experiment.
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This work was supported by an NIH Biotechnology Training grant and by the Center on Polymer Interfaces and Macromolecular Assemblies, which is sponsored by the NSF Materials Research Science and Engineering Center program under grant DMR-9400354
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This work was supported by an NIH Biotechnology Training grant and by the Center on Polymer Interfaces and Macromolecular Assemblies, which is sponsored by the NSF Materials Research Science and Engineering Center program under grant DMR-9400354.
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