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Volumn 16, Issue 20, 1997, Pages 4248-4250

The aza-cope rearrangement in transition metal complexes. Construction of an unsaturated C7-ligand from butadiyne and an allylic amine

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EID: 0000931923     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9704511     Document Type: Article
Times cited : (56)

References (45)
  • 3
    • 5244362225 scopus 로고
    • Stang, P. J., Diederich, F., Eds.; VCH: Weinheim, Chapter 11 and references cited therein
    • Iwamura, H.; Matsuda K. in Modem Acetylene Chemistry; Stang, P. J., Diederich, F., Eds.; VCH: Weinheim, 1995; Chapter 11 and references cited therein.
    • (1995) Modem Acetylene Chemistry
    • Iwamura, H.1    Matsuda, K.2
  • 13
    • 5244284889 scopus 로고
    • and references cited therein
    • (a) Bruce, M. I. Chem. Rev. 1991, 91, 197 and references cited therein,
    • (1991) Chem. Rev. , vol.91 , pp. 197
    • Bruce, M.I.1
  • 32
    • 5244290515 scopus 로고    scopus 로고
    • note
    • 5Ru: C, 60.85; H, 5.43; N, 1.13. Found: C, 60.57; H, 5.24; N, 1.12.
  • 33
    • 5244321709 scopus 로고    scopus 로고
    • note
    • 2, which could not be localized or considered as disordered or partially occupied. The packing diagram reveals tubular channels formed by the hydrophobic phenyl rings of the dppm ligands. We assume that the solvent resides in these channels.
  • 34
    • 0004082223 scopus 로고
    • Universiät Göttingen, Göttingen, Germany
    • Sheldrick, G. M. Program SHELXL93, Universiät Göttingen, Göttingen, Germany, 1993.
    • (1993) Program SHELXL93
    • Sheldrick, G.M.1
  • 35
    • 5244308952 scopus 로고    scopus 로고
    • note
    • 5Ru: C, 59.78; H, 4.84; N, 1.18. Found: C, 59.05; H, 4.82; N, 1.21.
  • 36
    • 5244273649 scopus 로고    scopus 로고
    • note
    • 2: C, 40.65; H, 7.17; N, 1.61. Found: C, 40.84; H, 6.94; N, 1.59.
  • 42
    • 5244375445 scopus 로고    scopus 로고
    • note
    • 2 (SHELXL93). With the exception of the solvent carbon atoms, all non-H atoms were refined with anisotropic thermal parameters. One phenyl ring (ratio 0.501(0.009)/0.499(0.009)), C10 (0.54(0.02)70.46(0.02)), C3x, C4-C7 (0.578(0.009)/0.422(0.009)) of the carbon chain and one solvent molecule (0.75(0.02)/0.25(0.02)) were found to be disordered; an additional solvent molecule was refined as "half-occupied". All hydrogen atoms were introduced at their geometric positions and treated according to the "riding model". Atomic coordinates, bond lengths and angles, and thermal parameters of 3a and 4a have been deposited at the Cambridge Crystallographic Data Centre, University Chemical Laboratory, Lens-field Road, Cambridge CB2 1EZ, UK (deposition no. CCDC-100-155).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.