The aza-cope rearrangement in transition metal complexes. Construction of an unsaturated C7-ligand from butadiyne and an allylic amine

Organometallics

Volumn 16, Issue 20, 1997, Pages 4248-4250

  Winter, Rainer F ^a   Hornung, Fridmann M ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000931923     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9704511     Document Type: Article

References (45)

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42. 2 (SHELXL93). With the exception of the solvent carbon atoms, all non-H atoms were refined with anisotropic thermal parameters. One phenyl ring (ratio 0.501(0.009)/0.499(0.009)), C10 (0.54(0.02)70.46(0.02)), C3x, C4-C7 (0.578(0.009)/0.422(0.009)) of the carbon chain and one solvent molecule (0.75(0.02)/0.25(0.02)) were found to be disordered; an additional solvent molecule was refined as "half-occupied". All hydrogen atoms were introduced at their geometric positions and treated according to the "riding model". Atomic coordinates, bond lengths and angles, and thermal parameters of 3a and 4a have been deposited at the Cambridge Crystallographic Data Centre, University Chemical Laboratory, Lens-field Road, Cambridge CB2 1EZ, UK (deposition no. CCDC-100-155).
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