Mechanistic study of the photoisomerization of Os3(CO)10(L) in which L (L=1,4-di-R-1,4-diazabutadiene (R-DAB) or pyridine-2-carbaldehyde N-R-imine (R-PyCa)) changes its coordination from σ, σ-N,N′ into σ-N, μ2-N′, η2-C=N′

Journal of Organometallic Chemistry

Volumn 572, Issue 2, 1999, Pages 271-281

  Nijhoff, Jos ^a   Bakker, Maarten J ^a   Hartl, František ^a   Stufkens, Derk J ^a  

^a UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

1,4 di R 1,4 Diazabutadiene; N R imine; Os3 clusters; Photisomerization; Pyridine 2 carbaldehyde

Indexed keywords

EID: 0000929052     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00955-3     Document Type: Article

References (37)

1. D.J. Stufkens, in: I. Bernal (Ed.), Stereochemistry of Organometallic and Inorganic Compounds, Elsevier, Amsterdam, 1989, p. 226.
2. Stiegman A.E., Tyler D.R. Coord. Chem. Rev. 63:1985;217.
3. Meyer T.J., Caspar J.V. Chem. Rev. 85:1985;187.
4. Geoffroy G.L., Wrighton M.S. Organometallic Photochemistry. 1979;Academic Press, New York.
5. Hepp A.F., Wrighton M.S. J. Am. Chem. Soc. 105:1983;5934.
6. Dunkin I.R., Harter P., Shields C.J. J. Am. Chem. Soc. 106:1984;7248.
7. van der Graaf T., Stufkens D.J., Oskam A., Goubitz K. Inorg. Chem. 30:1991;599.
8. Kokkes M.W., Stufkens D.J., Oskam A. Inorg. Chem. 24:1985;4411.
9. Stufkens D.J. Comments Inorg. Chem. 13:1992;359.
10. Morse D.L., Wrighton M.S. J. Am. Chem. Soc. 98:1976;3931.
11. Luong J.C., Faltynek R.A., Wrighton M.S. J. Am. Chem. Soc. 102:1980;7892.
12. Luong J.C., Faltynek R.A., Wrighton M.S. J. Am. Chem. Soc. 101:1979;1597.
13. Stufkens D.J. Coord. Chem. Rev. 104:1990;39.
14. Kokkes M.W., de Lange W.G.J., Stufkens D.J., Oskam A. J. Organomet. Chem. 294:1985;59.
15. Kokkes M.W., Stufkens D.J., Oskam A. Inorg. Chem. 24:1985;2934.
16. Andréa R.R., de Lange W.G.J., Stufkens D.J., Oskam A. Inorg. Chem. 28:1989;318.
17. van Dijk H.K., Stufkens D.J., Oskam A. Inorg. Chem. 28:1989;75.
18. van Dijk H.K., van der Haar J., Stufkens D.J., Oskam A. Inorg. Chem. 28:1989;75.
19. Servaas P.C., Stor G.J., Stufkens D.J., Oskam A. Inorg. Chim. Acta. 178:1990;185.
20. van der Graaf T., van Rooy A., Stufkens D.J., Oskam A. Inorg. Chim. Acta. 187:1991;133.
21. van Outersterp J.W.M., Stufkens D.J., Vlček A. Jr Inorg. Chem. 34:1995;5183.
22. Rossenaar B.D., Lindsay E., Stufkens D.J., Vlček A. Jr Inorg. Chim. Acta. 250:1996;5.
23. Nieuwenhuis H.A., van Loon A., Moraal M.A., Stufkens D.J., Oskam A., Goubitz K. J. Organomet. Chem. 492:1995;165.
24. Aarnts M.P., Stufkens D.J., Wilms M.P., Baerends E.J., Vlček A. Jr., Clark I.P., George M.W., Turner J.J. Chem. Eur. J. 2:1996;1556.
25. Aarnts M.P., Stufkens D.J., Vlček A. Jr Inorg. Chim. Acta. 266:1997;37.
26. van der Graaf T., Hofstra R.M.J., Schilder P.G.M., Rijkhoff M., Stufkens D.J., van der Linden J.G.M. Organometallics. 10:1991;3668.
27. van Outersterp J.W.M., Garriga Oostenbrink M.T., Nieuwenhuis H.A., Stufkens D.J., Hartl F. Inorg. Chem. 34:1995;6312.
28. Nijhoff J., Bakker M.J., Hartl F., Stufkens D.J., Fu W.-F., van Eldik R. Inorg. Chem. 37:1998;661.
29. E. Hunstock, F. Hartl, M.J. Calhorda (manuscript in preparation).
30. Zoet R., van Koten G., Vrieze K., Duisenberg A.J.M., Spek A.L. Inorg. Chim. Act. 148:1988;71.
31. Zoet R., Jastrzebski J.T.B.H., van Koten G., Mahabiersing T., Vrieze K., Heÿdenrÿk D., Stam C.H. Organometallics. 7:1988;2108.
32. Kleverlaan C.J., Hartl F., Stufkens D.J. J. Photochem. Photobiol. A: Chem. 103:1997;231.
33. J. Nijhoff, PhD Thesis, Universiteit van Amsterdam, 1998.
34. Víchová J., Hartl F., Vlček A. Jr J. Am. Chem. Soc. 114:1992;10903.
35. J. Nijhoff, F. Hartl, D.J. Stufkens, J. Fraanje (manuscript in preparation).
36. H.G. Heller, J.R. Langan, J. Chem. Soc. Perkin Trans. II (1981) 341.
37. S.o.C.a.A.C. Aberchromics Ltd., College of Cardiff, University of Wales.