Phosphorescence and Structure of a Tetrameric Copper(I)-Amide Cluster

Inorganic Chemistry

Volumn 37, Issue 15, 1998, Pages 3785-3791

  James, Alicia M ^a   Laxman, Ravi K ^a   Fronczek, Frank R ^a   Maverick, Andrew W ^a  

^a LOUISIANA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000917193     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971341p     Document Type: Article

References (45)

1. Hampden-Smith, M. J.; Kodas, T. T. In The Chemistry of Metal CVD; Kodas, T. T., Hampden-Smith, M. J., Eds.; VCH: Weinheim, Germany, 1994; Chapter 5.
2. 2.
3. Jeffries, P. M.; Girolami, G. S. Chem. Mater. 1989, 1, 8-10.
4. Beach, D. B.; LeGoues, F. K.; Hu, C.-K. Chem. Mater. 1990, 2, 216-219.
5. For a discussion of applications and techniques of light-induced thin film deposition, see: Ibbs, K. G., Osgood, R. M., Eds. Laser Chemical Processing for Microelectronics; Cambridge University Press: Cambridge, U.K., 1989.
6. Dupuy, C. G.; Beach, D. B.; Hurst, J. E., Jr.; Jasinski, J. M. Chem. Mater. 1989, 1, 16-18.
7. Jones, C. R.; Houle, F. A.; Kovac, C. A.; Baum, T. H. Appl. Phys. Lett. 1985, 46, 97-99. Wilson, R. J.; Houle, F. A. Phys. Rev. Lett. 1985, 55, 2184-2187.
8. Jones, C. R.; Houle, F. A.; Kovac, C. A.; Baum, T. H. Appl. Phys. Lett. 1985, 46, 97-99. Wilson, R. J.; Houle, F. A. Phys. Rev. Lett. 1985, 55, 2184-2187.
9. Houle, F. A.; Wilson, R. J.; Baum, T. H. J. Vac. Sci. Technol. 1986, A4, 2452-2458.
10. Markwalder, B.; Widmer, M.; Braichotte, D.; Van den Bergh, H. J. Appl. Phys. 1989, 65, 2470-2474.
11. Han, J.; Jensen, K. F. J. Appl. Phys. 1994, 75, 2240-2250.
12. Chen, Y. D.; Reisman, A.; Turlik, I.; Temple, D. J. Electrochem. Soc. 1995, 142, 3911-3918.
13. Kutal, C. Coord. Chem. Rev. 1990, 99, 213-252.
14. Lappert, M. F.; Power, P. P.; Sanger, A. R.; Srivastava, R. C. Metal and Metalloid Amides; Horwood: Chichester, England, 1980.
15. Baxter, D. V.; Chisholm, M. H.; Gama, G. J.; Hector, A. L.; Parkin, I. P. Adv. Mater. 1995, 7, 49-51.
16. Miele, P.; Foulon, J. D.; Hovnanian, N.; Durand, J.; Cot. L. Eur. J. Solid State Inorg. Chem. 1992, 29, 573-583.
17. Hursthouse, M. B. Personal communication. Cited In: Lappert, M. F.; Power, P. P.; Sanger, A. R.; Srivastava, R. C. Metal and Metalloid Amides; Horwood: Chichester, England, 1980; p 493.
18. Bradley, D. C. Unpublished work. Cited In: ten Hoedt, R. W. M.; Noltes, J. G.; van Koten, G.; Spek, A. L. J. Chem. Soc., Dalton Trans. 1978, 1800-1806.
19. Bürger, H.; Wannagat, U. Monatsh. Chem. 1964, 95, 1099-1102.
20. Fair, C. K. MolEN: An Interactive Structure Solution Procedure; Enraf-Nonius: Delft, The Netherlands, 1990.
21. Beurskens, P. T. Dirdif: Technical Report 1984/1; Crystallography Laboratory, Toernooiveld, Nijmegen, The Netherlands, 1984.
22. This reactor is similar to one we have used previously (Kumar, R.; Fronczek, F. R.; Maverick, A. W.; Lai, W. G.; Griffin, G. L. Chem. Mater. 1992, 4, 577-582), except that its susceptor is 2.5 cm in diameter.
23. Hitchcock, P. B.; Lappert, M. F.; Pierssens, L. J.-M. Chem. Commun. 1996, 1189-1190.
24. Geerts, R. L.; Huffman, J. C.; Folting, K.; Lemmen, T. H.; Caulton, K. G. J. Am. Chem. Soc. 1983, 105, 3503-3506.
25. Pitt, C. G.; Fowler, M. S. J. Am. Chem. Soc. 1967, 89, 6792-6793. Kirichenko, É. A.; Ermakov, A. I.; Pimkin, N. I.; Andrianov, K. A.; Kopylov, V. M.; Shkol'nik, M. I. J. Gen. Chem. USSR 1979, 49, 1333-1336.
26. Pitt, C. G.; Fowler, M. S. J. Am. Chem. Soc. 1967, 89, 6792-6793. Kirichenko, É. A.; Ermakov, A. I.; Pimkin, N. I.; Andrianov, K. A.; Kopylov, V. M.; Shkol'nik, M. I. J. Gen. Chem. USSR 1979, 49, 1333-1336.
27. Harvey, P. D.; Gray, H. B. J. Am. Chem. Soc. 1988, 110, 2145-2147.
28. Porterfield, W. W. Inorganic Chemistry: A Unified Approach, 2nd ed.; Academic Press: New York, 1993; p 214.
29. We thank a reviewer for alerting us to the likely importance of metal-metal interactions in this cluster.
30. Vogler, A.; Kunkely, H. Chem. Phys. Lett. 1988, 150, 135-137.
31. If the prominent absorption and emission bands are associated with different electronic transitions, we might expect to find some evidence in the cluster's absorption spectrum (300-500 nm) for the spin-allowed partner of the phosphorescence transition. We found no such evidence, even in more concentrated solutions, although these experiments were limited somewhat by the low solubility of the cluster in common solvents.
32. Vogler, A.; Kunkely, H. J. Am. Chem. Soc. 1986, 108, 7211-7212.
33. Vitale, M.; Palke, W. E.; Ford, P. C. J. Phys. Chem. 1992, 96, 8329-8336. See also: Kyle, K. R.; Ryu, C. K.; DiBenedetto, J. A.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 5132-5137.
34. Vitale, M.; Palke, W. E.; Ford, P. C. J. Phys. Chem. 1992, 96, 8329-8336. See also: Kyle, K. R.; Ryu, C. K.; DiBenedetto, J. A.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 5132-5137.
35. Yam, V. W.-W.; Lee, W.-K.; Lai, T.-F. J. Chem. Soc., Chem. Commun. 1993, 1571-1573.
36. Rath, N. P.; Holt, E. M.; Tanimura, K. Inorg. Chem. 1985, 24, 3934-3938. Rath, N. P.; Holt, E. M.; Tanimura, K. J. Chem. Soc., Dalton Trans. 1986, 2303-2310. Jasinski, J. P.; Rath, N. P.; Holt, E. M. Inorg. Chim. Acta 1985, 97, 91-97.
37. Rath, N. P.; Holt, E. M.; Tanimura, K. Inorg. Chem. 1985, 24, 3934-3938. Rath, N. P.; Holt, E. M.; Tanimura, K. J. Chem. Soc., Dalton Trans. 1986, 2303-2310. Jasinski, J. P.; Rath, N. P.; Holt, E. M. Inorg. Chim. Acta 1985, 97, 91-97.
38. Rath, N. P.; Holt, E. M.; Tanimura, K. Inorg. Chem. 1985, 24, 3934-3938. Rath, N. P.; Holt, E. M.; Tanimura, K. J. Chem. Soc., Dalton Trans. 1986, 2303-2310. Jasinski, J. P.; Rath, N. P.; Holt, E. M. Inorg. Chim. Acta 1985, 97, 91-97.
39. Stevenson, K. L.; Braun, J. L.; Davis, D. D.; Kurtz, K. S.; Sparks, R. I. Inorg. Chem. 1988, 27, 3472-3476.
40. Payne, S. A.; Goldberg, A. B.; McClure, D. S. J. Chem. Phys. 1983, 78, 3688-3697.
41. Harvey, P. D. Inorg. Chem. 1995, 34, 2019-2024.
42. -1.
43. Timpson, C. J.; Carter, C. C.; Olmsted, J., III. J. Phys. Chem. 1989, 93, 4116-4120.
44. Demas, J. N.; Harris, E. W.; McBride, R. P. J. Am. Chem. Soc. 1977, 99, 3547-3551.
45. Yamamoto, T.; Ehara, Y.; Kubota, M.; Yamamoto, A. Bull. Chem. Soc. Jpn. 1980, 53, 1299-1302.