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Volumn 44, Issue 13, 1988, Pages 4259-4275

Trimethylsilyl trifltate catalyzed aldol-type reaction of enol silyl ethers and acetals or related compounds

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Indexed keywords


EID: 0000914963     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)86671-0     Document Type: Article
Times cited : (175)

References (81)
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    • 2, -78 °C, 0.5 h) gave trimethylsilyl ethers of 34d (82%, erythro:threo = 73:27) and 34e (86%, erythro:threo = 69:31), respectively.
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    • Reaction of carbonyl compounds with powerful nucleophiles proceeds through such hypervalent silicon Intermediates. See
    • (1981) Chemistry Letters , pp. 375
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    • Some decrease in selectivity in reaction of 41 and 5c by the use of TMSOTf/amine is perhaps due to higher temperature
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    • 2a


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