A Bis-Capped Cofacial Metallodiporphyrin: Synthesis and Electrochemistry of a Molecule Containing Two Coaxial Metal-Metal Multiple Bonds in Close Proximity

Inorganic Chemistry

Volumn 35, Issue 26, 1996, Pages 7922-7923

  Collman, James P ^a   Fish, H T ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000903784     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950940y     Document Type: Article

References (17)

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2. (b) Collman, J. P.; Barnes, C. E.; Swepston, P. N.; Ibers, J. A. J. Am. Chem. Soc. 1984, 106, 3500.
3. (c) Collman, J. P.; Barnes, C. E.; Woo, L. K. Proc. Natl. Acad. Sci. U.S.A. 1983, 80, 7684.
4. (d) Collman, J. P.; Garner, J. M.; Woo, L. K. J. Am. Chem. Soc. 1989, 111, 8141.
5. (a) Collman, J. P.; Arnold, H. J.; Fitzgerald, J. P.; Weissman, K. J. J. Am. Chem. Soc. 1993, 115, 9309.
6. (b) Arnold, H. J.; Collman, J. P.; Marchon, J. M.; Maldivi, P.; Yee, G. T.; Miller, J. S. J. Am. Chem. Soc., submitted for publication.
7. (c) Collman, J. P.; Arnold, H. J.; Weissman, K. J.; Burton, J. M. J. Am. Chem. Soc. 1994, 116, 9761.
8. (a) Collman, J. P.; Kim, K.; Garner, J. M. J. Chem. Soc., Chem. Commun. 1986, 1711.
9. (b) Collman, J. P.; Garner, J. M. J. Am. Chem. Soc. 1990, 112, 166.
10. The following abbreviations are used throughout this note. DPA is the tetraanion of 1,8-bis{5-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrinyl]anthracene. OEP and OETAP are the dianions of octaethyl porphyrin and octaethyl tetraazaporphyrin respectively. Cp is the cyclopentadienyl anion.
11. Cayton, R. H.; Chisholm, M. H.; Huffman, J. C.; Lobkovsky, E. B. J. Am. Chem. Soc. 1991, 113, 8709.
12. Redox potentials were collected vs observed ferrocene/ferrocenium redox couple at 0.339 V vs Ag/AgCl. Redox couples are reported vs NHE, which is assumed to be -0.197 V vs Ag/AgCl.
13. (a) Cotton, F. A.; Curtis, N. F.; Harris, C. B.; Johnson, B. F. G.; Lippard, S. J.; Mague, J. T.; Robinson, W. R.; Wood, J. S. Science 1964, 145, 1305.
14. (b) Cotton, F. A.; Curtis, N. F.; Johnson, B. F. G.; Robinson, W. R. Inorg. Chem. 1965, 4, 326.
15. (e) Cotton, F. A.; Harris, C. B. Inorg. Chem., 1965, 4, 330.
16. (d) Cotton, F. A. Inorg. Chem. 1965, 4, 334.
17. Figgis, B. N.; Martin, R. L. J. Chem. Soc. 1956, 3837.