Substituent Effects on Thermochemical Properties of C-, N-, O-, and S-Centered Radicals. Physical Interpretation of Substituent Effects

Journal of Chemical Information and Computer Sciences

Volumn 39, Issue 6, 1999, Pages 1057-1063

  Cherkasov, Artem ^a   Jonsson, Mats ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000894262     PISSN: 00952338     EISSN: None     Source Type: Journal    
DOI: 10.1021/ci990424g     Document Type: Article

References (11)

1. Visiting scientist 1998, 1999. Present address: Biochemistry Faculty, University of Saskatchewan, Wiggins Road 107, Saskatoon, S7N 5E5 Canada.
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3. Cherkasov, A.; Jonsson, M. Substituent Effect on Thermochemical Properties of Free Radicals. New Substituent Scales for C-Centered Radicals. J. Chem. Inf. Comput. Sci. 1998, 38, 1151-1156.
4. Data taken from NIST Standard Reference Database Number 69, March 1998 Release.
5. Galkin, V. I.; Sayakhov, R. D.; Cherkasov, R. A. Steric Effect: The Problem of Quantitative Estimation and Appearance in the Reactivity of Organoelement Compounds. Usp. Khim. (Russ. Chem. Rev.) 1991, 60, 1617-1641.
6. Cherkasov, A. R.; Galkin, V. I.; Cherkasov, R. A.; A New Approach to Theoretical Estimation of Inductive Constants. J. Phys. Org. Chem. 1998, 11, 437-447.
7. Cherkasov, A. R.; Galkin, V. I.; Cherkasov. R. A. "Inductive" Electronegativity Scale. J. Mol. Struct. (THEOCHEM) in press.
8. Taft, R. W. Linear Steric Relationships. J. Am. Chem. Soc. 1953, 75, 5, 4538-4539.
9. Clark, K. B.; Wayner, D. D. M. Are Relative Bond Energies a Measure of Radical Stabilization Energies? J. Am. Chem. Soc. 1991, 113, 9363-9365.
10. Jonsson, M.; Lind, J.; Merényi, G.; Eriksen, T. E. Remote Substituent Effects on Polar and Nonpolar Covalent Bonds. J. Chem. Soc., Perkin Trans. 2 1994, 2149-2154.
11. Jonsson, M.; Lind, J.; Merényi, G.; Eriksen, T. E. Redox Properties of 4-Substituted Aryl Methyl Chalcogenides in Water. J. Chem. Soc., Perkin Trans. 2 1995, 67-70.