Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones using chiral oxazolinylferrocenylphosphines and one of their Ru(II) complex

Journal of Organometallic Chemistry

Volumn 572, Issue 2, 1999, Pages 163-168

  Arikawa, Yasuyoshi ^a   Ueoka, Masanao ^a   Matoba, Kazutaka ^a   Nishibayashi, Yoshiaki ^b   Hidai, Masanobu ^b   Uemura, Sakae ^a  

^a KYOTO UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

Crystal structure; Oxazolinylferrocenylphosphine; Ruthenium(II) complex; Transfer hydrogenation

Indexed keywords

EID: 0000890434     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00948-6     Document Type: Article

References (17)

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7. Y. Arikawa, M. Ueoka, H. Takada, K. Ohe, S. Uemura, Abstract II, 72nd Annual Meeting of the Chemical Society of Japan, Tokyo, March 1997, p. 810.
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9. 2 leads to diminished yields and enantioselectivities.
10. Y. Nishibayashi, S. Uemura, Synlett (1995) 79.
11. Nishibayashi Y., Segawa K., Arikawa Y., Ohe K., Hidai M., Uemura S. J. Organomet. Chem. 545-546:1997;381.
12. 2(Pybox-irpo)(CO) have been reported to be 2.097(6) and 2.083(5): H. Nishiyama, Y. Itoh, Y. Sugawara, H. Matsumoto, K. Aoki, K. Itoh, Bull. Chem. Soc. Jpn. 68 (1995) 1247.
13. 6 has been reported to be 2.118(4): D.L. Davies, J.F. Shaun, A. Garratt, D.R. Russell, Chem. Commun. (1997) 1351.
14. 2 have been reported to be 2.294(4) and 2.231(5): P. Barbaro, C. Bianchini, A. Togni, Organometallics 16 (1997) 3004.
15. The bond length of Ru-P in CpRuCl[(R)-(S)-PPFA]·EtOH has been reported to be 2.294(3): Y. Nishibayashi, Y. Kurobe, I. Takei, M. Hidai, unpublished result.
16. The author has deposited atomic co-ordinates, thermal parameters, bond distances and angles for the X-ray structure of 6 with the Cambridge Crystallographic Data Center. These data can be obtained, on request, from the Director, Cambridge Crystallographic Data Center, 12 Union Road, Cambridge, CB2 1EZ, UK.
17. TEXSAN: Crystal Structure Analysis Package. Molecular Structure, 1985 and 1992.