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Volumn 109, Issue 19, 1987, Pages 5749-5759

Dynamic Behavior of Dicobalt Hexacarbonyl Propargyl Cations and Their Reactions with Chiral Nucleophiles

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EID: 0000882082     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00253a030     Document Type: Article
Times cited : (181)

References (21)
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    • For a recent example and leading references, see; (b) Platinum complex (Figure 1): Bennett, M. A.; Yoshida, T. J. Am. Chem. Soc. 1978, 100, 1750.
    • For a recent example and leading references, see; (a) Buchwald, S. L.; Lum, R. T.; Dervan, J. C. J. Am. Chem. Soc. 1986, 108, 7441. (b) Platinum complex (Figure 1): Bennett, M. A.; Yoshida, T. J. Am. Chem. Soc. 1978, 100, 1750.
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    • Trinuclear and tetranuclear cobalt complexes of acetylene are also known, see
    • Trinuclear and tetranuclear cobalt complexes of acetylene are also known, see: Dickson, R. S.; Fraser, P. J. Adv. Organomet. Chem. 1974, 12, 323.
    • (1974) J. Adv. Organomet. Chem. , vol.12 , pp. 323
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    • In Organic Synthesis via Metal Carbonyls
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    • (b) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett., 25, 2555. (c) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett. 1983, 24, 2239. (d) Padmanabhan, S.; Nicholas, K. M. J. Organomet. Chem. 1981, 212, 115. (e) O'Boyle, J. E.; Nicholas, K. M. Tetrahedron Lett. 1980, 21, 1595. (f) Padmanabhan, S.; Nicholas, K. M. Syn. Commun. 1980, 10, 503. (g) Nicholas, K. M.; Mulvaney, M.; Bayer, M. J. Am. Chem. Soc. 1980, 102, 2508. (h) Hodes, H. D.; Nicholas, K. M. Tetrahedron Lett. 1978, 19, 439. (i) Lockwood, R. F.; Nicholas, K. M. Tetrahedron Lett. 1977, 18, 4163. (j) For a recent application to the total synthesis of (±)-cyclocolorenone see: Saha, M.; Bogby. B.; Nicholas, K. M. Tetrahedron Lett. 1986, 27, 915. Halper, Ed.; Academic; New York
    • Nicholas, K. M.; Nestle, M. O.; Seyferth, D. Transition Metal Organometallics: Halper, Ed.; Academic; New York, 1978; Vol. 2, p 1. (b) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett. 1982, 25, 2555. (c) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett. 1983, 24, 2239. (d) Padmanabhan, S.; Nicholas, K. M. J. Organomet. Chem. 1981, 212, 115. (e) O'Boyle, J. E.; Nicholas, K. M. Tetrahedron Lett. 1980, 21, 1595. (f) Padmanabhan, S.; Nicholas, K. M. Syn. Commun. 1980, 10, 503. (g) Nicholas, K. M.; Mulvaney, M.; Bayer, M. J. Am. Chem. Soc. 1980, 102, 2508. (h) Hodes, H. D.; Nicholas, K. M. Tetrahedron Lett. 1978, 19, 439. (i) Lockwood, R. F.; Nicholas, K. M. Tetrahedron Lett. 1977, 18, 4163. (j) For a recent application to the total synthesis of (±)-cyclocolorenone see: Saha, M.; Bogby. B.; Nicholas, K. M. Tetrahedron Lett. 1986, 27, 915.
    • (1982) Transition Metal Organometallics , vol.2 , pp. 1
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    • unpublished results of M. T. Klimas. Prepared by the procedure of
    • (b) Mo-Re: Beck, W.; Muller, H. J. ; Nagel. U. Angew. Chem., Int. Ed. Engl. 1986, 25, 734. (c) Ni2-Fe: Tilney-Bassett. J. F. J. Chem. Soc. 1963, 4784.
    • Ni-Co; unpublished results of M. T. Klimas. Prepared by the procedure of: Freeland, B. H.; Hux, J. E.; Payne, N. C.; Tyers, K. G. Inorg. Chem. 1980, 19, 693. (b) Mo-Re: Beck, W.; Muller, H. J. ; Nagel. U. Angew. Chem., Int. Ed. Engl. 1986, 25, 734. (c) Ni2-Fe: Tilney-Bassett. J. F. J. Chem. Soc. 1963, 4784.
    • (1980) Inorg. Chem. , vol.19 , pp. 693
    • Freeland, B.H.1    Hux, J.E.2    Payne, N.C.3    Tyers, K.G.4
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    • (b) Schilling. B. F. R.; Hoffmann. R. Tetrahedron Lett. 1979, 101, 3456.
    • Schilling, B. E. R.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 6274. (b) Schilling. B. F. R.; Hoffmann. R. Tetrahedron Lett. 1979, 101, 3456.
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    • (b) Magnus. P.: Becker. D. P. J. Chem. Soc., Chem. Commun. 1985. 640.
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    • The value of AG* in ref 10a was reported incorrectly
    • We thank Professor Nicholas for a helpful exchange of information relevant to this issue. Activation energies were determined by use of the Eyring equation for site exchange, see: Lukehart, C. M. Fundamental Transition Metal Organometallic Chemistry: Brookes/Cole: Montery
    • The value of AG* in ref 10a was reported incorrectly. We thank Professor Nicholas for a helpful exchange of information relevant to this issue. Activation energies were determined by use of the Eyring equation for site exchange, see: Lukehart, C. M. Fundamental Transition Metal Organometallic Chemistry: Brookes/Cole: Montery, 1985; p 200.
    • (1985) , pp. 200
  • 18
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    • (b) For a discussion of the fluxional properties of π-allyl palladium complexes, see; Auburn, P. R.; Mackenzie, P. B.; Bosnich, B. J. Am. Chem. Soc. 1985,107, 2033. Mackenzie, P. B.; Whelan, J.; Bosnich, B. J. Am. Chem. Soc. 1985, 107, 2046.
    • Uemura, M.; Minami, T.; Isobe, K.; Kobayashi, T.; Hayashi, Y. Tetrahedron Lett. 1986, 27, 967. (b) For a discussion of the fluxional properties of π-allyl palladium complexes, see; Auburn, P. R.; Mackenzie, P. B.; Bosnich, B. J. Am. Chem. Soc. 1985,107, 2033. Mackenzie, P. B.; Whelan, J.; Bosnich, B. J. Am. Chem. Soc. 1985, 107, 2046.
    • (1986) Tetrahedron Lett. , vol.27 , pp. 967
    • Uemura, M.1    Minami, T.2    Isobe, K.3    Kobayashi, T.4    Hayashi, Y.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.