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Trinuclear and tetranuclear cobalt complexes of acetylene are also known, see
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Nicholas, K. M.; Nestle, M. O.; Seyferth, D. Transition Metal Organometallics: Halper, Ed.; Academic; New York, 1978; Vol. 2, p 1. (b) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett. 1982, 25, 2555. (c) Padmanabhan, S.; Nicholas, K. M. Tetrahedron Lett. 1983, 24, 2239. (d) Padmanabhan, S.; Nicholas, K. M. J. Organomet. Chem. 1981, 212, 115. (e) O'Boyle, J. E.; Nicholas, K. M. Tetrahedron Lett. 1980, 21, 1595. (f) Padmanabhan, S.; Nicholas, K. M. Syn. Commun. 1980, 10, 503. (g) Nicholas, K. M.; Mulvaney, M.; Bayer, M. J. Am. Chem. Soc. 1980, 102, 2508. (h) Hodes, H. D.; Nicholas, K. M. Tetrahedron Lett. 1978, 19, 439. (i) Lockwood, R. F.; Nicholas, K. M. Tetrahedron Lett. 1977, 18, 4163. (j) For a recent application to the total synthesis of (±)-cyclocolorenone see: Saha, M.; Bogby. B.; Nicholas, K. M. Tetrahedron Lett. 1986, 27, 915.
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Ni-Co; unpublished results of M. T. Klimas. Prepared by the procedure of: Freeland, B. H.; Hux, J. E.; Payne, N. C.; Tyers, K. G. Inorg. Chem. 1980, 19, 693. (b) Mo-Re: Beck, W.; Muller, H. J. ; Nagel. U. Angew. Chem., Int. Ed. Engl. 1986, 25, 734. (c) Ni2-Fe: Tilney-Bassett. J. F. J. Chem. Soc. 1963, 4784.
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The value of AG* in ref 10a was reported incorrectly
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We thank Professor Nicholas for a helpful exchange of information relevant to this issue. Activation energies were determined by use of the Eyring equation for site exchange, see: Lukehart, C. M. Fundamental Transition Metal Organometallic Chemistry: Brookes/Cole: Montery
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The value of AG* in ref 10a was reported incorrectly. We thank Professor Nicholas for a helpful exchange of information relevant to this issue. Activation energies were determined by use of the Eyring equation for site exchange, see: Lukehart, C. M. Fundamental Transition Metal Organometallic Chemistry: Brookes/Cole: Montery, 1985; p 200.
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(b) For a discussion of the fluxional properties of π-allyl palladium complexes, see; Auburn, P. R.; Mackenzie, P. B.; Bosnich, B. J. Am. Chem. Soc. 1985,107, 2033. Mackenzie, P. B.; Whelan, J.; Bosnich, B. J. Am. Chem. Soc. 1985, 107, 2046.
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Uemura, M.; Minami, T.; Isobe, K.; Kobayashi, T.; Hayashi, Y. Tetrahedron Lett. 1986, 27, 967. (b) For a discussion of the fluxional properties of π-allyl palladium complexes, see; Auburn, P. R.; Mackenzie, P. B.; Bosnich, B. J. Am. Chem. Soc. 1985,107, 2033. Mackenzie, P. B.; Whelan, J.; Bosnich, B. J. Am. Chem. Soc. 1985, 107, 2046.
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