Unprecedented conversion of benzylideneanilines into aryl isocyanides promoted by a low-valent molybdenum complex. X-ray structure of trans-[Mo(CNPh)(N2)(Ph2PCH2CH 2PPh2)2]

Organometallics

Volumn 17, Issue 6, 1998, Pages 1010-1012

  Nakamura, Goh ^a,b   Harada, Yuji ^a,b   Arita, Chirima ^a   Seino, Hidetake ^a   Mizobe, Yasushi ^a   Hidai, Masanobu ^b  

^a INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000878439     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9711281     Document Type: Article

References (30)

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3. See, for example: (a) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115. (b) Hidai, M.; Ishii, Y. Bull. Chem. Soc. Jpn. 1996, 69, 819.
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13. 6 were obtained by essentially the same procedure in 52% and 46% yields, respectively.
14. 6 (0.73 mol/ mol of 1a), indicating that both C-C and C-H bond cleavage occurs on the benzylidene carbon.
15. 6).
16. w) = 0.036 (0.024) for 7090 data with I > 3.0σ(I) and anisotropic refinements of the model with idealized hydrogen atoms.
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18. 15
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30. Reaction of the W analogue 1b with PhCH=NPh seems to produce only an iminoacyl complex 7b (M = W) instead of a corresponding W isocyanide-dinitrogen complex, although assignment of 7b is still tentative.