Formation of Dinitrogen by Oxidation of [(bpy)2(NH3)RuORu(NH3)(bpy)2] 4+

Inorganic Chemistry

Volumn 35, Issue 8, 1996, Pages 2167-2168

  Ishitani, Osamu ^a,b   White, Peter S ^a   Meyer, Thomas J ^a  

^a University of North Carolina at Chapel Hill   (United States)

^b SAITAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000871933     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9512643     Document Type: Article

References (23)

1. Pell, S. D.; Armor, J. N. J. Am. Chem. Soc. 1975, 97, 5012
2. (a) Thompson, M. S.; Meyer, T. J. J. Am. Chem. Soc. 1981, 103, 5577-5578.
3. (b) Murphy, W. R., Jr.; Takeuchi, K. J.; Berley, M. H.; Meyer, T J. Inorg. Chem. 1987, 25, 2197.
4. (a) Gersten, S W.; Samuels, G. J.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4029-4030.
5. (b) Gilbert, J. A.; Eggleston, D. S.; Murphy, W. R., Jr., Geselowitz, D. A.; Gersten, S. W.; Hodgson, D. J.; Meyer, T J. J. Am. Chem. Soc. 1985, 107, 3855-3864.
6. Kutner, W.; Gilbert, J. A.; Tomaszewski, A.; Meyer, T. J.; Murray, R. W. J. Electroanal. Chem. Interfacial Electrochem. 1986, 205, 185-207.
7. Doppelt, P.; Meyer, T. J. Inorg. Chem. 1987, 26, 2027-2034.
8. (e) Dobson, J. C.; Sullivan, B. P.; Doppelt, P.; Meyer, T. J. Inorg. Chem. 1988, 27, 3863-3866.
9. (f) Raven, S. J.; Meyer, T. J. Inorg. Chem. 1988, 27, 4478-4483.
10. (g) Geselowitz, D.; Meyer, T. J Inorg. Chem 1990, 29, 3892-3896.
11. Phelps, D. W.; Kahn, M.; Hodgson, D. J. Inorg. Chem. 1975, 14, 2486-2490.
12. (a) Hurst, J. K.; Zhou, J.; Lei, Y. Inorg. Chem. 1992, 31, 1010-1017.
13. (b) Comte, P.; Nazeeruddin, M. K.; Rotzinger, F. P.; Frank, A. J., Gratzel, M. J. Mol. Catal. 1989, 52, 63-84.
14. - salt of the hydroxo ammine has been characterized by elemental analysis and X-ray structure determination (Ishitani, O. Work in progress).
15. u = 0.045 Attempts to refine the structure in Cc failed to improve the agreement factors, indicating C2/C as the correct choice of space group.
16. f is the formal potential and n and m are the number of electrons and protons transferred for the half-reaction See, for example, ref 4b.
17. IV may be inappropriate.
18. 2 were less than stoichiometric A yield as high as 87% was obtained in a series of three experiments.
19. Ni, J.; Binstead, R.; Chronister, C. Work in progress.
20. (a) Coia, G M.; White, P. S.; Meyer, T. J.; Wink, D. A.; Keefer, L. K.; Davis, W. M. J. Am. Chem. Soc. 1994, 116, 3649-3650.
21. (b) Pipes, D. W., Bakir, M.; Vitols, S. E.; Hodgson, D. J.; Meyer, T. J. J Am. Chem. Soc 1990, 112, 5507-5514.
22. Except for the expected variations in peak current, changing the concentration of 2 had no influence on voltammetric wave shapes; thus the N-N coupling chemistry appears to be intramolecular
23. Collman, J. P.; Hutchison, J. E.; Ennis, M. S.; Lopez, M. A., Guilard, R. J. Am. Chem. Soc. 1992, 114, 8074-8080.