Complexes containing unbridged dative metal-metal bonds and the strong acceptor Ru(CO)3(SiCl3)2 moiety. Comments on the transition metal to silicon bond

Organometallics

Volumn 17, Issue 26, 1998, Pages 5810-5819

  Jiang, Faming ^a   Male, Jonathan L ^a   Biradha, Kumar ^b   Leong, Weng Kee ^c   Pomeroy, Roland K ^a   Zaworotko, Michael J ^b  

^a SIMON FRASER UNIVERSITY   (Canada)

^b SAINT MARY S UNIVERSITY   (Canada)

^c NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000848387     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980116s     Document Type: Review

References (86)

1. Einstein, F. W. B.; Pomeroy, R. K.; Rushman, P.; Willis, A. C. J. Chem. Soc., Chem. Commun. 1983, 854.
2. (a) Del Paggio, A. A.; Muetterties, E. L.; Heinekey, D. M.; Day. V. W.; Day, C. S. Organometallics 1986, 5, 575.
3. (b) Arndt, L. W.; Darensbourg, M. Y.; Delord, T.; Bancroft, B. T. J. Am. Chem. Soc. 1986, 108, 2617.
4. (c) Roberts, D. A.; Mercer, W. C.; Geoffroy, G. L.; Pierpont, C. G. Inorg. Chem. 1986, 25, 1439.
5. Usón, R.; Forniés, J.; Espinet, P.; Fortuño, C.; Tomas, M.; Welch, A. J. J. Chem. Soc., Dalton Trans. 1988, 3005.
6. Davis, H. B.; Einstein, F. W. B.; Glavina, P. G.; Jones, T.; Pomeroy, R. K.; Rushman, P. Organometallics 1989, 8, 1030.
7. Fleming, M. M.; Pomeroy, R. K.; Rushman, P. J. Organomet. Chem. 1984, 278, C33.
8. Einstein, F. W. B.; Jennings, M. C.; Krentz, R.; Pomeroy, R. K.; Rushman, P.; Willis, A. C. Inorg. Chem. 1987, 26, 1341.
9. (a) Martin, L. R.; Einstein, F. W. B.; Pomeroy, R. K. Organometallics 1988, 7, 294.
10. (b) Einstein, F. W. B.; Johnston, V. J.; Ma, A. K.; Pomeroy, R. K. Organometallics 1990, 9, 52.
11. (a) Einstein, F. W. B.; Pomeroy, R. K.; Rushman, P.; Willis, A. C. Organometallics 1985, 4, 250.
12. (b) Batchelor, R. J.; Davis, H. B.; Einstein, F. W. B.; Pomeroy, R. K. J. Am. Chem. Soc. 1990, 112, 2036.
13. (c) Batchelor, R. J.; Einstein, F. W. B.; Pomeroy, R. K.; Shipley, J. A. Inorg. Chem. 1992, 31, 3155.
14. (a) Male, J. L. Ph.D. Thesis, Simon Fraser University, 1996.
15. (b) Male, J. L.; Jiang, F.; Pomeroy, R. K. To be published.
16. Pomeroy, R. K.; Gay, R. S.; Evans, G. O.; Graham, W. A. G. J. Am. Chem. Soc. 1972, 94, 272.
17. Pomeroy, R. K.; Wijesekera, K. S. Inorg. Chem. 1980, 19, 3729.
18. Martin, L. R.; Einstein, F. W. B.; Pomeroy, R. K. Inorg. Chem. 1985, 24, 2777.
19. (a) Chen, L.; Poë, A. J. Inorg. Chem. 1989, 28, 3641.
20. (b) L'Eplattenier, F.; Calderazzo, F. Inorg. Chem. 1968, 7, 1290.
21. (c) Cobbledick, R. G.; Einstein, F. W. B.; Pomeroy, R. K.; Spetch, E. R. J. Organomet. Chem. 1980, 195, 77.
22. Albers, M. O.; Colville, N. J. J. Chem. Soc., Dalton Trans. 1982, 1069.
23. Shipley, J. A.; Batchelor, R. J.; Einstein, F. W. B.; Pomeroy, R. K. Organometallics 1991, 10, 3620.
24. Gabe, E. J.; LePage, Y.; Charland, J.-P.; Lee, F. L.; White, P. S. J. Appl. Crystallogr. 1989, 22, 384.
25. Watkin, D. J.; Carruthers, J. R.; Betteridge, P. W. CRYSTALS; Chemical Crystallography Laboratory, University of Oxford: Oxford, England, 1985.
26. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1975; Vol. IV, p 99 (present distributor Kluwer Academic: Dordretcht, The Netherlands).
27. Sheldrick, G. M. SHELXTL; Siemens: Madison, WI 1995.
28. Chalk, K. L.; Pomeroy, R. K. Inorg. Chem. 1984, 23, 444.
29. (a) Churchill, M. R.; Hollander, F. J.; Hutchinson, J. P. Inorg. Chem. 1977, 16, 2655.
30. (b) Churchill, M. R.; DeBoer, B. G. Inorg. Chem. 1977, 16, 878.
31. Willis, A. C.; van Buuren, G. N.; Einstein, F. W. B.; Pomeroy, R. K. Inorg. Chem. 1983, 22, 1162.
32. See also: (a) Howard, J. A. K.; Kellet, S. C.; Woodward, P. J. Chem. Soc., Dalton Trans. 1975, 2332.
33. (b) Cook, N.; Smart, L.; Woodward, P. J. Chem. Soc., Dalton Trans. 1977, 1744.
34. Hsu, L.-Y.; Bhattacharyya, N.; Shore, S. G. Organometallics 1985, 4, 1483.
35. Wang, W.; Batchelor, R. J.; Einstein, F. W. B.; Lu, C.-Y.; Pomeroy, R. K. Organometallics 1993, 12, 3598.
36. t ligands) on the donor atom to Ru(2) is 3.20(1)-3.42(1) Å for 3Fe; 3.35(1)-3.50(1) Å for 3Ru; and 3.37-(1)-3.61(1) Å for 3Os.
37. Tolman, C. A. Chem. Rev. 1977, 77, 313.
38. 29 To illustrate the difference, we place an arrow between the Os and W atoms consistent with the Lewis acid-base character of the bond.
39. Haaland, A. Angew. Chem., Int. Ed. Engl. 1989, 28, 992.
40. Male, J. L.; Pomeroy, R. K.; Tyler, D. R. Organometallics 1997, 16 (6), 3431.
41. Emsley, J. The Elements; Clarendon: Oxford, 1989.
42. Bhattacharyya, N.; Coffy, T. J.; Quintana, W.; Salupo, T. A.; Bricker, J. C.; Shay, T. B.; Payne, M.; Shore, S. G. Organometallics 1990, 9, 2368.
43. (a) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193.
44. (b) Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th ed.; Wiley: New York, 1988; p 62.
45. (a) Harris, G. W.; Boeyens, J. C. A.; Coville, N. J. Organometallics 1985, 4, 914.
46. (b) Giordano, R.; Sappa, E.; Tiripicchio A.; Tiripicchio Camellina, M.; Mays, M. J.; Brown, M. P. Polyhedron 1989, 8, 1855.
47. (c) Treichel, P. M. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Elmsford, NY, 1982; Vol. 4, p 11, and references therein.
48. (d) Boag, N. M.; Kaesz, H. D. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Elmsford, NY, 1982; Vol. 4, p 171, and references therein.
49. (d) Harvey, P. D.; Butler, I. S.; Barreto, M. de C. W.; Coville, N. J.; Harris, G. Inorg. Chem. 1988, 27, 639.
50. The complexes do decompose slowly in air, but this can probably be attributed to the sensitivity of the SiCl bonds to moisture.
51. 20
52. (a) Atwood, J. D. Inorganic and Organometallic Reaction Mechanisms, 2nd ed.; Wiley: New York, 1997.
53. (b) Basolo, F. Polyhedron 1990, 9, 1503.
54. (a) Huheey, J. E.; Keiter, E. A.; Keiter, R. L. Inorganic Chemistry, 4th ed.; HarperCollins: New York, 1993; pp 336-341.
55. (b) Drago, R. S.; Wong, N.; Ferris, D. C. J. Am. Chem. Soc. 1991, 113, 1970.
56. (c) Drago, R. S.; Ferris, D. C.; Wong, N. J. Am. Chem. Soc. 1990, 112, 8953.
57. (a) Kristjánsdóttir, S. S.; Norton, J. R. In Transition Metal Hydrides: Recent Advances in Theory and Experiment; Dedieu, A., Ed.; VCH: New York, 1991.
58. (b) Angelici, R. J. Acc. Chem. Res. 1995, 28, 51.
59. 12
60. (a) Connor, J. A. In Metal Clusters in Catalysis; Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam, 1986; Chapter 3.
61. (b) Johnson, B. F. G.; Roberts, Y. V. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed., Wiley: Chicester, 1994; Vol. 4, p 2177.
62. Nakatsuji, H.; Hada, M.; Kawashima, A. Inorg. Chem. 1992, 31, 1740.
63. Aylett, B. J. Prog. Inorg. Chem. Radiochem. 1982, 25, 1.
64. Lichtenberger, D. L.; Rai-Chaudhuri, A. J. Am. Chem. Soc. 1991, 113, 2923.
65. Novak, I.; Huang, W.; Luo, L.; Huang, H. H.; Ang, H. G.; Zybill, C. E. Organometallics 1997, 16, 1567.
66. Hübler, K.; Hunt, P. A.; Maddock, S. M.; Rickard, C. E. F.; Roper, W. R.; Salter, D. M.; Schwerdtfeger; P.; Wright, L. J. Organometallics 1997, 16, 5076.
67. It is also very unlikely that the difference is due to steric effects. In 3Fe and 3Os the difference in the two types of Ru-Si lengths in each molecule is virtually the same (∼0.07 Å) despite the much longer M-Ru length in the osmium derivative (2.984(1) versus 2.930(1) Å).
68. Jetz, W.; Graham, W. A. G. J. Am. Chem. Soc. 1967, 89, 2773.
69. (a) Xiao, S.-X.; Trogler, W. C.; Ellis, D. E.; Berkovitch-Yellin, Z. J. Am. Chem. Soc. 1983, 105, 7033.
70. (b) Marynick, D. S. J. Am. Chem. Soc. 1984, 106, 4064.
71. (c) Wheeler, R. A.; Hoffmann, R.; Strähle, J. J. Am. Chem. Soc. 1989, 108, 5381.
72. Krentz, R.; Pomeroy, R. K. Inorg. Chem. 1985, 24, 2976.
73. Orpen, A. G.; Connelly, N. G. J. Chem. Soc., Chem. Commun. 1985, 1310.
74. Einstein, F. W. B.; Jones, T. Inorg. Chem. 1982, 21, 987.
75. Whitla, W. A.; Graham, W. A. G. Unpublished results. See footnote 34 of ref 53.
76. Vancea, L.; Bennett, M. J.; Jones, C. E.; Smith, R. A.; Graham, W. A. G. Inorg. Chem. 1977, 16, 897.
77. Martin, L. R.; Einstein, F. W. B.; Pomeroy, R. K. Unpublished results.
78. (a) Manojlovic-Muir, L.; Muir, K. W.; Ibers, J. A. Inorg. Chem. 1970, 9, 447.
79. (b) Yao, Z.; Klabunde, K. J.; Asirvatham, A. S. Inorg. Chem. 1995, 34, 5289.
80. (c) Hansen, V. M.; Batchelor, R. J.; Einstein, F. W. B.; Male, J. L.; Pomeroy, R. K.; Zaworotko, M. J. Organometallics 1997, 16, 4875.
81. Ball, R.; Bennett, M. J. Inorg. Chem. 1972, 8, 1806.
82. (a) Crozat, M. M.; Watkins, S. F. J. Chem. Soc., Dalton Trans. 1972, 2512.
83. (b) Howard, J.; Woodward, P. J. Chem. Soc., Dalton Trans. 1975, 59.
84. (c) Harris, P. J.; Howard, J. A. K.; Knox, S. A. R.; McKinney, R. J.; Phillips, R. P.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Dalton Trans. 1978, 403.
85. (d) Goddard, R.; Woodward, P. J. Chem. Soc., Dalton Trans. 1980, 559.
86. 3 structures there is also no systematic variation in the SiCl lengths to indicate a major participation of SiCl σ* molecular orbitals in the FeSi bonds, although as with the Ru compounds there is considerable variation in SiCl lengths within individual SiCl3 ligands.