Synthesis and Structural Characterization of Lithium Thiolates: Dependence of Association and Aggregation on Donor Hapticity and Ligand Size and Synthesis of the First Trimeric Lithium Thiolate [Li(THF)SR]3 and the Solvent-Separated Ion Pair [Li(12-crown-4)2][SR] (R = 2,4,6-tBu3C6H2)1

Inorganic Chemistry

Volumn 35, Issue 20, 1996, Pages 5820-5827

  Ruhlandt Senge, Karin ^a   Englich, Ulrich ^a   Senge, Mathias O ^b   Chadwick, Scott ^a  

^a SYRACUSE UNIVERSITY   (United States)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000840064     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960375e     Document Type: Article

References (44)

1. This work is dedicated to Professor Kurt Dehnicke on the occasion of his 65th birthday.
2. Pauer, F.; Power, P. P. In Lithium Chemistry. A Theoretical and Experimental Overview; Sapse, A.-M., Schleyer, P. v. R., Eds.; Wiley: New York, 1995; p 295.
3. Dilworth, J. R.; Hu, J. Adv. Inorg. Chem. 1993, 40, 411.
4. Hitchcock, P. B.; Lappert, M. F.; Samways, B. J.; Weinberg, E. J. J. Chem. Soc., Chem. Commun. 1983, 1492.
5. Millar, M.; Lee, J. F.; Koch, S. A.; Fikar, R. Inorg. Chem. 1982, 21, 4105.
6. Fikar, R.; Koch, S. A.; Millar, M. Inorg. Chem. 1985, 24, 3311.
7. Dilworth, J. R.; Hutchinson, J.; Zubieta, J. A. J. Chem. Soc., Chem. Commun. 1983, 1034.
8. Blower, P. J.; Dilworth, J. R.; Zubieta, J. A. Inorg. Chem. 1985, 24, 2866.
9. Koch, S. A.; Millar, M. J. Am. Chem. Soc. 1983, 105, 3362.
10. Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 2633.
11. Sigel, G. A.; Power, P. P. Inorg. Chem. 1987, 26, 2819.
12. Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1991, 30, 3683.
13. Du Mont, W.-W.; Kubinok, S.; Lange, L.; Pohl, S.; Saak, W.; Wagner, I. Chem. Ber. 1991, 124, 1315.
14. Bonasia, P. J.; Arnold, J. J. Organomet. Chem. 1993, 449, 147.
15. Ruhlandt-Senge, K.; Power, P. P. Bull. Soc. Chim. Fr. 1992, 129, 594.
16. Bannister, A. J.; Clegg, W.; Gill, W. R. J. Chem. Soc., Chem. Commun. 1987, 850.
17. Aslam, M.; Bartlett, R. A.; Block, E.; Olmstead, M. M.; Power, P. P.; Sigel, G. A. J. Chem. Soc., Chem. Commun. 1985, 1674.
18. Flick, K. E.; Bonasia, P. J.; Gindelberger, D. E.; Katari, J. E. B.; Schwanz, D. Acta Crystallogr. 1994, C50, 674.
19. Becker, G.; Klinkhammer, K. W.; Lartiges, S.; Böttcher, P.; Poll, W. Z. Anorg. Allg. Chem. 1992, 613, 7.
20. Bonasia, P. J.; Christou, V.; Arnold, J. J. Am. Chem. Soc. 1993, 115, 6777.
21. Bonasia, P. J.; Gindelberger, D. E.; Daboussi, B. O.; Arnold, J. J. Am. Chem. Soc. 1992, 114, 5209.
22. 2, 3, was briefly mentioned in a review article, but details regarding synthesis or structure were not published: Shoner, S.; Power, P. P. Unpublished results.
23. Ellison, J. J.; Power, P. P. Inorg. Chem. 1994, 33, 4231.
24. Khasnis, D. V.; Bureta, M.; Emge, T. J.; Brennan, J. G. J. Chem. Soc., Dalton Trans. 1995, 45.
25. Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1993, 32, 4505.
26. Becker, G.; Klinkhammer, K. W.; Massa, W. Z. Anorg. Allg. Chem. 1993, 619, 628.
27. Janssen, M. D.; Rijnberg, E.; de Wolf, C. A.; Hogerheide, M. P.; Kruis, D.; Kooijman, H.; Spek, A. L.; Grove, D. M.; van Koten, G. Inorg. Chem., in press.
28. (a) Baas, J. M. A.; van Bekkum, H.; Hofnagel, M. A.; Wepster, B. M. Recl. Trav. Chim. Pays-Bas 1969, 88, 1110.
29. (b) Rundel, W. Chem. Ber. 1968, 101, 2956.
30. Blower, P. J.; Dilworth, J. R.; Hutchinson, J. P.; Zubieta, J. A. J. Am. Chem. Soc., Dalton Trans. 1985, 1533.
31. Hope, H. Progr. Inorg. Chem. 1994, 41, 1.
32. Parkin, S.; Moezzi, B.; Hope, H. XABS2: an empirical absorption correction program. J. Appl. Crystallogr. 1995, 28, 53.
33. Sheldrick, G. M. SHELXTL-Plus: A program package for crystal structure solution and refinement. University of Göttingen, Germany, 1990.
34. Sheldrick, G. M. SHELXL-93: Program for crystal structure refinement. University of Göttingen, Germany, 1993.
35. Wilson, A. J. C., Ed. International Tables for Crystallography, Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C.
36. Cromer, D. T.; Mann, J. B. Acta Crystallogr. 1968, A24, 321.
37. Cromer, D. T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891.
38. (a) van der Schaaf, P. A.; Hogerheide, M. P.; Grove, D. M.; Spek, A. L.; van Koten, G. J. Chem. Soc., Chem. Commun. 1992, 1703.
39. van der Schaaf, P. A.; Jastrzebski, J. T. B. H.; Hogerheide, M. P.; Smeets, W. J. J.; Spek, A. L.; Boersma, J.; van Koten, G. Inorg. Chem. 1993, 32, 4111.
40. Tatsumi, K.; Inoue, Y.; Nakamura, A.; Cramer, R. E.; VanDoorne, W.; Gilje, J. W. Angew. Chem., Int. Ed Engl. 1990, 29, 422.
41. Chadwick, S.; Englich, U.; Ruhlandt-Senge, K. Submitted.
42. Hope, H.; Olmstead, M. M.; Power, P. P.; Xu, X. J. Am. Chem. Soc. 1984, 106, 819.
43. Bartlett, R. A.; Power, P. P. J. Am. Chem. Soc. 1987, 109, 6509.
44. Power, P. P. Acc. Chem. Res. 1988, 21, 147.