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Volumn 25, Issue 47, 1984, Pages 5389-5392

A new synthetic approach to the bicyclo[5.3.1]undecane ring system in taxanes

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[No Author keywords available]

Indexed keywords


EID: 0000819824     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)91292-4     Document Type: Article
Times cited : (39)

References (18)
  • 11
    • 84918414186 scopus 로고    scopus 로고
    • 1H-NMR (200MHz or 400MHz), high resolution mass spectroscopy and/or combustion analysis.
  • 13
    • 84918414185 scopus 로고    scopus 로고
    • Stereochemistry of the hydroxyl group at C(2) was determined by measurement of intramolecular hydrogen bonding between the hydroxyl group at C(2) and the methoxymethyl ether at C(14) in the high dilution IR spectrum of i, which was derived from the compound 11.
  • 15
    • 84918414184 scopus 로고    scopus 로고
    • The stereoselectivity was found to be rather sensitive to the reaction temperature and the solvent used.
  • 16
    • 84918414183 scopus 로고    scopus 로고
    • 1H-NMR (400MMz).
  • 17
    • 84918414182 scopus 로고    scopus 로고
    • Stereoselective reduction of the ketone group at C(2) in 15 was explained by the less hindered side hydride attack.
  • 18
    • 84918414181 scopus 로고    scopus 로고
    • The corresponding bicyclic compound with E olefin was not detected in the reaction product.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.