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(Formula presented) the excited-state lifetime, should not change significantly while the interatomic separation where the initial excitation takes place is one order of magnitude smaller
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(Formula presented) the excited-state lifetime, should not change significantly while the interatomic separation where the initial excitation takes place is one order of magnitude smaller.
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Note that over a large range of (Formula presented) values (Formula presented) (Formula presented) such that the loss rate of Cs atoms due to Cs-Cs collisions is much larger than that due to Na-Cs collisions
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Note that over a large range of (Formula presented) values (Formula presented) (Formula presented) such that the loss rate of Cs atoms due to Cs-Cs collisions is much larger than that due to Na-Cs collisions.
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22
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85037210872
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Ideally, it would have been better to measure process (i) directly but the 6-Å separation of the Na (Formula presented) and (Formula presented) lines and rate of FS changing collisions make such a measurement extremely difficult. We also attempted to measure this rate by multiphoton ionization of the collision fragments, but the signal was obscured by the molecular structure near the atomic resonances
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Ideally, it would have been better to measure process (i) directly but the 6-Å separation of the Na (Formula presented) and (Formula presented) lines and rate of FS changing collisions make such a measurement extremely difficult. We also attempted to measure this rate by multiphoton ionization of the collision fragments, but the signal was obscured by the molecular structure near the atomic resonances.
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29
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0041457637
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Here a time-dependent magnetic field associated with rotation of the collision axis induces an electronic spin flip
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