trans-Difluorosilicon(IV) Complexes of Tetra-p-tolylporphyrin and Tetrakis(p-(trifluoromethyl)phenyl)porphyrin: Crystal Structures and Unprecedented Reactivity in Hexacoordinate Difluorosilanes

Inorganic Chemistry

Volumn 36, Issue 7, 1997, Pages 1354-1359

  Kane, Kevin M ^a,c   Lemke, Frederick R ^a   Petersen, Jeffrey L ^b  

^a OHIO UNIVERSITY   (United States)

^b WEST VIRGINIA UNIVERSITY   (United States)

^c UNIVERSITY OF IDAHO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000803703     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960639x     Document Type: Article

References (81)

1. 2
2. Kane, K. M. Dissertation, Ohio University, 1996.
3. Tandura, S. N.; Alekseev, N. V.; Voronkov, M. G. Top. Curr. Chem. 1986, 131, 99-189.
4. Corriu, R. J. P.; Young, J. C. In The Silicon-Heteroatom Bond; Patai, S., Rappaport, Z., Eds.; John Wiley & Sons: New York, 1991; pp 49-66.
5. Corriu, R. J. P.; Young, C. J. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappaport, Z., Eds.; John Wiley & Sons: New York. 1989; pp 1241-1288.
6. Kumada, M.; Tamao, K.; Yoshida, J. I. J. Organomet. Chem. 1982, 239, 115-132.
7. Bassindale, A. G.; Taylor, P. G. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappaport, Z., Eds.; John Wiley and Sons: New York, 1989; pp 839-892.
8. Sheldrick, W. S. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappaport, Z., Eds.; John Wiley and Sons: New York, 1989; pp 227-303.
9. Klebe, G.; Tran Qui, D. Acta Crystallogr. 1984, C40, 476-479.
10. Adley, A. D.; Bird, P. H.; Fraser, A. R.; Onyszchuk, M. Inorg. Chem. 1972, 11, 1402-1409.
11. Kummer, D.; Balkir, A.; Köster, H. J. Organomet. Chem. 1979, 178, 29-54.
12. Campbell-Ferguson, H. J.; Ebsworth, E. A. V. J. Chem. Soc. A 1967, 705-712.
13. Brelière, C.; Corriu, R. J. P.; Royo, G.; Man, W. C.; Zwecker, J. Organometallics 1990, 10, 2633-2635.
14. Carré, F.; Chuit, C.; Corriu, R. J. P.; Mehdi, A.; Reyé, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 1097-1099.
15. Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371-1448.
16. Brelière, C.; Corriu, R. J. P.; Royo, G.; Zwecker, J. Organometallics 1989, 8, 1834-1836.
17. Brelière, C.; Carré, F.; Corriu, R. J. P.; Poirier, M.; Royo, G.; Zwecker, J. Organometallics 1989, 8, 1831-1833.
18. Breilière, C.; Carré, F.; Corriu, R. J. P.; Royo, G. Organometallics 1988, 7, 1006-1008.
19. Carré, F.; Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Réyé, C. Angew. Chem., Int. Ed. Engl. 1989, 28, 489-491.
20. Hoard, J. L. Ann. N.Y. Acad. Sci. 1973, 206, 18-31.
21. Hoard, J. L. Science 1971, 174, 1295-1302.
22. Buchler, J. In Porphyrins and Metalloporphyrins; Smith, K. M., Ed.; Eisevier: Amsterdam, 1975.
23. Sayer, P.; Gouterman, M.; Connell, C. R. Acc. Chem. Res. 1982, 15, 73-79.
24. Scheidt, W. R. In The Porphyins; Dolphin, D., Ed.; Academic Press, Inc.: New York, 1978; Vol. 3; pp 463-511.
25. Dolphin, D., Ed. The Porphyrins; Academic Press, Inc.: New York, 1978.
26. Thomas, A. L. Phthalocynine Research and Applications; CRC Press: Boca Raton, FL, 1990.
27. Miyamoto, T. K.; Sugita, N.; Matsumoto, Y.; Sasaki, Y.; Konno, M. Chem. Lett. 1983, 1695-1698.
28. Balch, A. L.; Cornman, C. R.; Olmstead, M. M. J. Am. Chem. Soc. 1990, 112, 2963-2969.
29. Guilard, R.; Barbe, J.; Boukhris, M.; Lecomte, C. J. Chem. Soc., Dalton Trans. 1988, 1921-1925.
30. Guilard, R.; Barbe, J.; Boukhris, A.; Lecomte, C.; Anderson, J. E.; Xu, Q. Y.; Kadish, K. M. J. Chem. Soc., Dalton Trans. 1988, 1109-1113.
31. Gouterman, M.; Schwartz, F. P.; Smith, P. D.; Dolphin, D. J. Chem. Phys. 1973, 59, 676-690.
32. Kadish, K. M.; Xu, Q. Y.; Barbe, J.; Anderson, J. E.; Wang, E.; Guilard, R. J. Am. Chem. Soc. 1987, 109, 7705-7714.
33. Barbe, J.; Guilard, R.; Lecomte, C.; Gerardin, R. Polyhedron 1984, 3, 889-894.
34. Cloutour C.; Lafargue, D.; Richards, J. A.; Pommier, J. J. Organomet. Chem. 1977, 137, 157-163.
35. Mavridis, A.; Tulinsky, A. Inorg. Chem. 1976, 15, 2723-2727.
36. Kane, A. R.; Yalman, R. G.; Kenney, M. E. Inorg. Chem. 1968, 7, 2588-2592.
37. Cloutour, C.; Lafargue, D.; Pommier, J. C. J. Organomet. Chem. 1980, 190, 35-42.
38. Maiya, G. B.; Barbe, J.; Kadish, K. M. Inorg. Chem. 1989, 28, 2524-2527.
39. Arnold, D. P.; Bartley, J. P. Inorg. Chem. 1994, 33, 1486-1490.
40. Barbe, J.; Ratti, C.; Richard, P.; Lecomte, C.; Gerardin, R.; Guilard, R. Inorg. Chem. 1990, 29, 4126-4130.
41. Arnold, D. P. Polyhedron 1998, 7, 2225-2227.
42. Smith, G.; Arnold, D. P.; Kennard, C. H. L.; Mak, T. C. W. Polyhedron 1991, 10, 509-516.
43. Cullen, D. L.; Meyer, E. F., Jr. Acta Crystallogr. 1973, B29, 2507 2515.
44. Lin, H.; Chen, J.; Hwang, L. Aust. J. Chem. 1991, 44, 747-751.
45. Collins, D. M.; Scheidt, W. R.; Hoard, J. L. J. Am. Chem. Soc. 1972, 94, 6689-6696.
46. Kato, S.; Noda, I.; Mizuta, M.; Itoh, Y. Angew. Chem. Soc. 1972, 94, 6689-6696.
47. Noda, I.; Kato, S.; Mizuta, M.; Yasuoka, N.; Kasai, N. Angew. Chem., Int. Ed. Engl. 1979, 18, 83.
48. Guilard, R.; Barbe, J. M.; Fahim, M.; Atmani, A.; Moninot, G.; Kadish, K. M. New J. Chem. 1992, 16, 815-820.
49. Arnold, D. P.; Morrison, E. A.; Hanna, J. V. Polyhedron 1990, 10, 1331-1336.
50. Arnold, D. P. Polyhedron 1986, 5, 1957-1963
51. Kadish, K. M.; Xu, Q. Y. Y.; Maiya, G. B.; Barbe, J.; Guilard, R. J. Chem. Soc., Dalton Trans. 1989, 1531-1536
52. Milgrom, L. R.; Sheppard, R. N. J. Chem. Soc., Chem. Commun. 1985, 350-351.
53. Arnold, D. P.; Tiekink, E. R. Polyhedron 1995, 14, 1785-1789.
54. Onaka, S.; Kondo, Y.; Yamashita, M.; Tatematsu, Y.; Kato, Y.; Goto, M.; Ito, T. Inorg. Chem. 1985, 24, 1070-1076.
55. Guilard, R.; Ratti, C.; Barbe, J.; Dubois, D.; Kadish, K. M. Inorg. Chem. 1991, 30, 1537-1542.
56. Kadish, K. M.; Swistak, C.; Boisselier-Cocolios, B.; Barbe, J. M.; Guilard, R. Inorg. Chem. 1986, 25, 4336-4343.
57. Cloutour, C.; Lafargue, D.; Pommier, J. C. J. Organomet. Chem. 1978, 161, 327-334.
58. Kadish, K. M.; Xu, Q. Y.; Barbe, J.; Guilard, R. Inorg. Chem. 1988, 27, 1191-1198.
59. Buchler, J. W.; Puppe, L.; Rohbock, K.; Schneehage, H. H. Chem. Ber 1973, 106, 2710-2732.
60. Marriot, P. J.; Gill, J. P.; Eglington, G. J. Chromatogr. 1982, 249, 291-310.
61. Kane, K. M.; Lemke, F. R.; Petersen, J. L. Inorg. Chem. 1995, 34, 4085-4091.
62. Scheidt, W. R.; Lee, Y. J. Struct. Bonding 1987, 64, 1-70.
63. Hoard, J. L. In Porphyrins and Metalloporphyrins; Smith, K. M., Ed., Elsevier: Amsterdam, 1975.
64. Meyer, E. F., Jr.; Cullen, D. In The Porphyrins; Academic Press: New York, 1978; Vol. 3; pp 513-529.
65. Smith, P. D.; James, B. R.; Dolphin, D. H. Coord. Chem. Rev. 1981, 39, 31-75.
66. Ebsworth, E. A. V. Volatile Silicon Compounds; Pergamon: Oxford, U.K., 1963; Vol. 4.
67. Van Dyke, C. H. The Bond to Halogens and Halogenoids; Marcel Dekker: New York, 1972; Vol. 2.
68. Kane, K. M.; Lorenz, C. R.; Heilman, D. M.; Lemke, F. R. Inorg. Chem. 1997, submitted for publication.
69. 17
70. Hancock, R. D.; Weaving, J. S.; Marques, H. M. J. Chem. Soc., Chem. Commun. 1989, 1176-1178.
71. Munro, O. Q.; Bradley, J. C.; Hancock, R. D.; Marques, H. M.; Marsicano, F.; Wade, P. W. J. Am. Chem. Soc. 1992, 114, 7218-7230.
72. Ravikanth, M.; Chandrashekar, T. K. Struct. Bonding 1995, 82, 105-188.
73. Renner, M. W.; Barkigia, K. M.; Zhang, Y.; Medforth, C. J.; Smith, K. M.; Fajer, J. J. Am. Chem. Soc. 1994, 116, 8582-8592.
74. Sparks, L. D.; Medforth, C. J.; Park, M.; Chamberlain, J. R., Ondrias, M. R.; Senge, M. O.; Smith, K. M.; Shelnutt, J. A. J. Am. Chem. Soc. 1993, 115, 581-592.
75. Yamamoto, Y.; Nadano, R.; Itagaki, M.; Akiba, K. J. Am. Chem. Soc. 1995, 117, 8287-8288.
76. 58
77. Balch, A. L.; Latos-Grazynski, L.; Noll, B. C.; Phillips, S. L. Inorg. Chem. 1993, 32, 1124-1129.
78. Lorenz, C. R.; Dewald, H. H.; Lemke, F. R. J. Electroanal. Chem. 1996, 415, 179-181.
79. XSCANS (version 2.0) is a diffractometer control system developed by Siemens Analytical X-ray Instruments, Madison, WI.
80. SHELXL-93 is a FORTRAN-77 program (Professor G. Sheldrick, Institut fur Anorganische Chemie, University at Göttingen, D-37077 Göttingen, Germany) for single-crystal X-ray structural analysis.
81. 1/2, where n is the number of reflections and P is the number of parameters varied during the last refinement cycle.