Electron Transfer. 134. Reduction of Bound Ruthenium(III) by Indium(I)

Inorganic Chemistry

Volumn 36, Issue 16, 1997, Pages 3485-3487

  Chandra, Swapan K ^a   Gould, Edwin S ^a  

^a KENT STATE UNIVERSITY   (United States)

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[No Author keywords available]

Indexed keywords

EID: 0000791555     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic961393z     Document Type: Article

References (40)

1. Sponsorship of this work by the National Science Foundation (Grant 93-14113) is gratefully acknowledged.
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5. See, for example: (a) Creutz, C.; Sutin, N. In Inorganic Reactions and Mechanisms; Zuckerman, J. J., Ed.; VCH Publishers: Deerfield Beach, FL, 1986; Vol. 5, p 50. (b) Haim, A. Prog. Inorg. Chem. 1983, 30, 441. (c) Bose, R. N.; Wagner, P. A.; Earley, J. E. Inorg. Chem. 1984, 23, 1132.
6. See, for example: (a) Creutz, C.; Sutin, N. In Inorganic Reactions and Mechanisms; Zuckerman, J. J., Ed.; VCH Publishers: Deerfield Beach, FL, 1986; Vol. 5, p 50. (b) Haim, A. Prog. Inorg. Chem. 1983, 30, 441. (c) Bose, R. N.; Wagner, P. A.; Earley, J. E. Inorg. Chem. 1984, 23, 1132.
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16. 10 all work with these complexes was carried out with quantities of 200 mg or less.
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19. Reactions carried out with In(I) in excess were sometimes complicated by precipitation of elemental ruthenium. In such cases, measurements were carried out with excess oxidant.
20. 5) on the heterocyclic ring. Strong autocatalysis was observed when such groups were at the 4-position, whereas profiles obtained with 3-substituted ligands of this type featured major segments in which reduction rates were very nearly independent of [In(I)], Further examination of these systems is in progress.
21. 17 indicate that it is ineffective as an inner-sphere redox bridge.
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31. III,II).
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34. (a) Both ionic radii and ionization enthalpies of the atoms have been tabulated by: Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th ed.; Wiley: New York, 1988: pp 1381, 1387. (b) See also: Shannon, R. D. Acta Crystallogr. 1976, A32, 751.
35. (a) Both ionic radii and ionization enthalpies of the atoms have been tabulated by: Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th ed.; Wiley: New York, 1988: pp 1381, 1387. (b) See also: Shannon, R. D. Acta Crystallogr. 1976, A32, 751.
36. Dronskowski, R. Inorg. Chem. 1994, 33, 5927.
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38. The approximate nature of this calculation does not justify a more elaborate treatment.
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