Temperature programmed desorption spectra of systems with concentration gradients in the solid lattice

Journal of Physical Chemistry

Volumn 100, Issue 27, 1996, Pages 11389-11395

  Mavrikakis, M ^a   Schwank, J W ^a   Gland, J L ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000790976     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9537623     Document Type: Article

References (18)

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11. Mavrikakis, M.; Schwank, J. W.; Gland J. L. Submitted to J. Chem. Phys.
12. 0 is the sticking probability at zero coverage, and P is the gas-phase pressure, with L and T being the crystal's thickness and temperature, respectively. Z represents the normalized thickness of the crystal, defined as Z = z/L, where z is the real-thickness variable (in cm), being zero at the bottom of the crystal and L (in cm) at the surface/bulk interface. The surface consists of the top layer of atoms of the crystal, and its thickness is taken to be zero in this model.
13. Smith, G. D. Numerical Solution of Partial Differential Equations; Clarendon Press: Oxford, 1985.
14. Franz, A.; Mavrikakis, M.; Gland, J. L. In preparation.
15. -10) Torr, unless otherwise stated.
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18. Mavrikakis, M.; Schwank, J. W.; Gland, J. L. In preparation.