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Isotactic PMMA (i-PMMA) has larger dimensions. Viscosity measurements suggest that i-PMMA chains are ca. 30% more extended than a-PMMA; see: Jenkins, R.; Porter, R. S. Polymer 1982, 23, 105-111.
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Brown, D. S.; Dawkins, J. V.; Farnell, A. S.; Taylor, G. Eur. Polym. J. 1987, 23, 463-467.
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Schillén K.; Classon, P. M.; Malmsten, M.; Linse, P.; Booth, C. J. Phys. Chem. B 1997, 101, 4238-4252, and references cited therein.
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