Reaction of Cp2Ti═CH2with Organic Halides: Evidence for a Radical Mechanism

Journal of the American Chemical Society

Volumn 107, Issue 6, 1985, Pages 1766-1768

  Buchwald, Stephen L ^a   Anslyn, Eric V ^a   Grubbs, Robert H ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000785942     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00292a056     Document Type: Article

References (12)

1. Grubbs, R. H. “Comprehensive Organometallic Chemistry”; Wilkinson, G., Stone, F. G. A., Abels, E. V., Eds.; 1982; Pergamon Press: Oxford; Chapter 54.
2. Brady, R. C., III; Pettit, R. J. Am. Chem. Soc. 1980, 102, 6181.
3. Green, M. L. H. Pure Appl. Chem. 1978, 50, 27–35.
4. Foger, K.; Anderson, J. R. J. Catal. 1978, 54, 318.
5. Fischer, E. O.; Maasbol, A. Angew. Chem., Int. Ed. Engl. 1964, 3, 580.
6. 2Cl under the same conditions. Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389.
7. Buchwald, S. L.; Cannizzo, L.; Clawson, L.; Ho, S.; Meinhart, D.; Stille, J. R.; Straus, D.; Grubbs, R. H. Pure Appl. Chem. 1984, 56, 1733.
8. (a) Waters, J. A.; Mortimer, G. A. J. Organomet. Chem. 1970, 22, 417. (b) Benzyl toslylate does not perform the same chemistry under these conditions.
9. Hartner, Jr., F. W.; Schwartz, J.; Cleft, S. M. J. Am. Chem. Soc. 1983, 705, 601.
10. Lau, K. S. Y.; Wong, P. K.; Stille, J. K. J. Am. Chem, Soc. 1976, 98, 5832.
11. Blackburn, T. F.; Labinger, J. A.; Schwartz, J. Tetrahdron Lett. 1975, 3041.
12. McCreary, M. D.; Lewis, D. W.; Wernick, D. L.; Whitesides, G. M. J. Am. Chem. Soc. 1974, 96, 1038.