Methodical studies for D/H-isotope analysis a new technique for the direct coupling of sample preparation to an IRMS

Isotopes in Environmental and Health Studies

Volumn 32, Issue 4, 1996, Pages 335-340

  Gehre, M ^a   Hofling R ^a   Kowski, P ^a  

^a HELMHOLTZ CENTRE FOR ENVIRONMENTAL RESEARCH UFZ   (Germany)

Author keywords

Chromium; Deuterium; Hydrogen; Isotope analysis; Isotope ratio; Natural abundances; Reduction; Water

Indexed keywords

EID: 0000781015     PISSN: 10256016     EISSN: None     Source Type: Journal    
DOI: 10.1080/10256019608234026     Document Type: Article

References (15)

1. J. Bigeleisen: M. L. Perlman and H. C . Prosser: Conversion of Hydrogenic Materials to Hydrogen for Isotopic Analysis. Anal. Chem. 24 (1952) 1356-1357.
2. Improvements in Means for the Quantitative Analysis of Deuterium in Hydrogenated Compounds. Patent Specification 904, 165, Aug. 27 (1959) No.29315/59, Patent Office London.
3. W. Rolle and H. Hübner: Einstufige Umarbeitung organischer Verbindungen in Wasserstoff zur massenspektrometrischen Isotopenanalyse. Fresenius Z. anal. Chemie. 232 (1967) 328.
4. A. Runge: Fortschritte bei der Probenchemie des Wasserstoffs für die Präzisionsisotopenanalyse an organischen Verbindungen und mineralisierten Wässern. Isotopenpraxis 16 (1980) 2.
5. M. L. Coleman, T. J. Shepherd, T. J. Durham, J. E. Rouse and G. R. Moore: Reduction of Water with Zinc for Hydrogen Isotope Analysis. Anal. Chem. 54 (1982) 993-995.
6. C. Kendall and T. B. Coplen: Multisample Conversion of Water to Hydrogen by Zinc for Stable Isotope Determination. Anal. Chem. 57 (1985) 1437-1440.
7. GSF-Jahresbericht 1987, 217-225.
8. 2-Water Equilibration Method: A Special Implication to Brines. Chem. Geol. (Isot. Geosci. Sect.) 72 (1988) 89-94.
9. J. Horita: Analytical Aspects of Stable Isotopes in Brines. Chem. Geol. (Isot. Geosci. Sect.) 79 (1989) 107-112
10. 2-Water Equilibration Methods with a Common Equilibration Setup. Appl. Radiat. Isot. 40 (1989) 801-805.
11. A. Tanweer: Importance of Clean Metallic Zinc for Hydrogen Isotope Analysis. Anal. Chem. 62 (1990) 2158-2160.
12. T. W. Vennemann and J. R. O'Neil: A Simple and Inexpensive Method of Hydrogen Isotope and Water Analyses of Minerals and Rocks Based on Zinc Reagent. Chem. Geol. (Isot. Geosci. Sect.) 103 (1993) 227-234.
13. A. Tanweer: Determination of Deuterium in Brines and in Hypersaline Aqueous Solutions by Mass Spectrometry Using Zinc as Reducing Agent. Analyst 118 (1993) 835-838.
14. M. Gehre, R. Höfling and P. Kowski: Verfahren und Vorrichtung zur on-line gekoppelten Deuteriumbestimmung. Patentschrift Aktenzeichen P 44 37 120. 9, Patentbüro Berlin, Deutschland (1994).
15. R. Gonfiantini: IAEA-REPORT: Advisory group meeting on stable isotope reference samples for geochemical and hydrological investigations. Vienna (1984) 77p.