One-step conversion of C-glycopyranosylnitromethanes to the corresponding methanal oximes

Synlett

Volumn , Issue 12, 1998, Pages 1319-1320

  Pham Huu, Duy Phong ^a   Petrušová, Mária ^a   BeMiller, James N ^b   Petruš, Ladislav ^a  

^a INSTITUTE OF CHEMISTRY   (Slovakia)

^b PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000779298     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-1950     Document Type: Article

References (25)

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16. 3SnH (1.2 ml, 4.50 mmol), and ABCN (30 mg) in benzene (5 ml) was stirred at 80°C for 2 h. After addition of another portion of ABCN (20 mg), reflux was continued for 1-4 h until no starting material could be detected (t.l.c., 3:2 hexane-ethyl acetate). Then the reaction mixture was cooled to room temperature and the solvent was removed under reduced pressure. Flash chromatography of the residue (silica gel) afforded 2a-e in 84-97% yields.
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19. 9 was used immediately without purification.
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