A2AuP2Se6 (A = K, Rb): Mixed-Valent Compounds with All Possible Coordination Geometries for Gold

Inorganic Chemistry

Volumn 35, Issue 12, 1996, Pages 3451-3452

  Chondroudis, Konstantinos ^a   McCarthy, Timothy J ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000771243     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9516020     Document Type: Article

References (20)

1. McCarthy, T. J.; Kanatzidis, M. G. Inorg. Chem. 1995, 34, 1257-1267 and references therein.
2. (a) McCarthy, T. J.; Kanatzidis, M. G. Chem. Mater. 1993, 5, 1061-1063.
3. (b) McCarthy, T. J.; Kanatzidis, M. G. J. Chem. Soc., Chem. Commun. 1994, 1089-1090.
4. (a) McCarthy, T. J.; Hogan, T. C.; Kannewurf, R.; Kanatzidis, M. G. Chem. Mater. 1994, 6, 1072-1079.
5. (b) McCarthy, T. J.; Kanatzidis, M. G. Inorg. Chem. 1995, 34, 1257-1267.
6. (a) Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1996, 35, 840-844.
7. (b) Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1995, 34, 5401-5402.
8. (c) Chondroudis, K.; Kanatzidis, M. G. Submitted.
9. Chen, J. H.; Dorhout, P. K. Inorg. Chem. 1995, 34, 5705-5706.
10. 6.2 (average on four data acquisitions).
11. W= 0.040/0.048.
12. Bronger, W.; Kathage, U. J. Alloys Compd. 1992, 184, 87-94.
13. 2.6, also studied with powder diffraction, has too many vacancies to allow one to unequivocally establish the true local coordination of gold. A full single-crystal crystallographic refinement is needed to establish the gold coordination in these materials. (a) Kojima, N.; Hasegawa, M.; Kitagawa, T.; Shimomura, O. J. Am. Chem. Soc. 1994, 116, 11368-11374. (b) Kitagawa, T.; Kojima, N.; Matsushita, N.; Ban, T.; Tsujikawa, I. J. Chem. Soc., Daltan Trans. 1991, 3115-3119.
14. 2.6, also studied with powder diffraction, has too many vacancies to allow one to unequivocally establish the true local coordination of gold. A full single-crystal crystallographic refinement is needed to establish the gold coordination in these materials. (a) Kojima, N.; Hasegawa, M.; Kitagawa, T.; Shimomura, O. J. Am. Chem. Soc. 1994, 116, 11368-11374. (b) Kitagawa, T.; Kojima, N.; Matsushita, N.; Ban, T.; Tsujikawa, I. J. Chem. Soc., Daltan Trans. 1991, 3115-3119.
15. Park, Y.; Kanatzidis, M. G. Angew. Chem., Int. Ed. Engl. 1990, 29, 914-915.
16. Kanatzidis, M. G. Chem. Mater. 1990, 2, 353-363.
17. Chondroudis, K.; Kanatzidis, M. G. Manuscript in preparation.
18. (a) Sheldrick, G. M. In Crystallographic Computing 3; Sheldrick, G. M.; Kruger, C., Doddard, R., Eds.; Oxford University Press: Oxford, England, 1985; pp 175-189.
19. (b) TEXSAN: Single Crystal Structure Analysis Software, Version 5.0; Molecular Structure Corp.: The Woodlands, TX 77381, 1981.
20. (c) Walker, N.; Stuart, D. Acta Crystallogr. 1983, A39, 158-166.