Supramolecular assemblies of metal complexes: Light-induced electron transfer in the galleries of α-zirconium phosphate

Journal of Physical Chemistry A

Volumn 102, Issue 28, 1998, Pages 5562-5568

  Kumar, C V ^a   Williams, Zeena J ^a   Turner, Rebecca S ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000752049     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9801323     Document Type: Article

References (69)

1. Lehn, J.-M. Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds. VCH: New York, 1991; pp 1. Balzani, V.; Scandola, F. Supramolecular Photochemistry; Ellis Horwood: New York, 1991. Baral, S.; Pendler, J. H.; Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part B pp 541. Webber, S. E.; Chem. Rev. 1990, 90, 1469.
2. Lehn, J.-M. Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds. VCH: New York, 1991; pp 1. Balzani, V.; Scandola, F. Supramolecular Photochemistry; Ellis Horwood: New York, 1991. Baral, S.; Pendler, J. H.; Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part B pp 541. Webber, S. E.; Chem. Rev. 1990, 90, 1469.
3. Lehn, J.-M. Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds. VCH: New York, 1991; pp 1. Balzani, V.; Scandola, F. Supramolecular Photochemistry; Ellis Horwood: New York, 1991. Baral, S.; Pendler, J. H.; Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part B pp 541. Webber, S. E.; Chem. Rev. 1990, 90, 1469.
4. Lehn, J.-M. Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds. VCH: New York, 1991; pp 1. Balzani, V.; Scandola, F. Supramolecular Photochemistry; Ellis Horwood: New York, 1991. Baral, S.; Pendler, J. H.; Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part B pp 541. Webber, S. E.; Chem. Rev. 1990, 90, 1469.
5. Turro, N. J.; Kavarnos, G. J. Chem. Rev. 1986, 86, 401. Baxter, S. M.; Jones, W. E.; E. Danielson, Worl, L.; Strouse, G.; Younathan, J.; Meyer, T. J. Coord. Chem. Rev. 1991, 111, 47. Fox, M. A.; Jones, W. E.; Watkins, D. M. Chem. and Eng. News 1993, 38. Fox, M. A.; Adv. Photochem. 1986, 13, 237.
6. Turro, N. J.; Kavarnos, G. J. Chem. Rev. 1986, 86, 401. Baxter, S. M.; Jones, W. E.; E. Danielson, Worl, L.; Strouse, G.; Younathan, J.; Meyer, T. J. Coord. Chem. Rev. 1991, 111, 47. Fox, M. A.; Jones, W. E.; Watkins, D. M. Chem. and Eng. News 1993, 38. Fox, M. A.; Adv. Photochem. 1986, 13, 237.
7. Turro, N. J.; Kavarnos, G. J. Chem. Rev. 1986, 86, 401. Baxter, S. M.; Jones, W. E.; E. Danielson, Worl, L.; Strouse, G.; Younathan, J.; Meyer, T. J. Coord. Chem. Rev. 1991, 111, 47. Fox, M. A.; Jones, W. E.; Watkins, D. M. Chem. and Eng. News 1993, 38. Fox, M. A.; Adv. Photochem. 1986, 13, 237.
8. Turro, N. J.; Kavarnos, G. J. Chem. Rev. 1986, 86, 401. Baxter, S. M.; Jones, W. E.; E. Danielson, Worl, L.; Strouse, G.; Younathan, J.; Meyer, T. J. Coord. Chem. Rev. 1991, 111, 47. Fox, M. A.; Jones, W. E.; Watkins, D. M. Chem. and Eng. News 1993, 38. Fox, M. A.; Adv. Photochem. 1986, 13, 237.
9. Gust, D.; Moore, T. Adv. Photochem. Volman, D., Hammond, G., Neckers, D., Eds.; Wiley: New York, 1991; Vol. 16. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
10. Gust, D.; Moore, T. Adv. Photochem. Volman, D., Hammond, G., Neckers, D., Eds.; Wiley: New York, 1991; Vol. 16. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
11. Gust, D.; Moore, T. Adv. Photochem. Volman, D., Hammond, G., Neckers, D., Eds.; Wiley: New York, 1991; Vol. 16. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
12. Vermeulen, L. A.; Snover, J. L.; Sapochak, L. S.; Thompson, M. E. J. Am. Chem. Soc. 1993, 115, 11767. Durr, H.; Bobman, S.; Beuerlein, A. J. J. Photochem. Photobiol. 1993, 73, 233. Gratzel, M. Acc. Chem. Res. 1981, 14, 376. Lehn, J.-M. Supramolecular Photochemistry; Balzani, V., Ed.; NATO ASI Series C; (Reidel: Dordecht, Netherlands, 1987; Vol. 214, p 29.
13. Vermeulen, L. A.; Snover, J. L.; Sapochak, L. S.; Thompson, M. E. J. Am. Chem. Soc. 1993, 115, 11767. Durr, H.; Bobman, S.; Beuerlein, A. J. J. Photochem. Photobiol. 1993, 73, 233. Gratzel, M. Acc. Chem. Res. 1981, 14, 376. Lehn, J.-M. Supramolecular Photochemistry; Balzani, V., Ed.; NATO ASI Series C; (Reidel: Dordecht, Netherlands, 1987; Vol. 214, p 29.
14. Vermeulen, L. A.; Snover, J. L.; Sapochak, L. S.; Thompson, M. E. J. Am. Chem. Soc. 1993, 115, 11767. Durr, H.; Bobman, S.; Beuerlein, A. J. J. Photochem. Photobiol. 1993, 73, 233. Gratzel, M. Acc. Chem. Res. 1981, 14, 376. Lehn, J.-M. Supramolecular Photochemistry; Balzani, V., Ed.; NATO ASI Series C; (Reidel: Dordecht, Netherlands, 1987; Vol. 214, p 29.
15. Vermeulen, L. A.; Snover, J. L.; Sapochak, L. S.; Thompson, M. E. J. Am. Chem. Soc. 1993, 115, 11767. Durr, H.; Bobman, S.; Beuerlein, A. J. J. Photochem. Photobiol. 1993, 73, 233. Gratzel, M. Acc. Chem. Res. 1981, 14, 376. Lehn, J.-M. Supramolecular Photochemistry; Balzani, V., Ed.; NATO ASI Series C; (Reidel: Dordecht, Netherlands, 1987; Vol. 214, p 29.
16. Whitten, D. G.; Spooner, S. P.; Hsu, Y.; Penner, P. L. Reactive Polymers; 1991, 15, 37. Mooney, W. F.; Whitten, D. G. J. Am. Chem. Soc. 1986, 108, 5712.
17. Whitten, D. G.; Spooner, S. P.; Hsu, Y.; Penner, P. L. Reactive Polymers; 1991, 15, 37. Mooney, W. F.; Whitten, D. G. J. Am. Chem. Soc. 1986, 108, 5712.
18. Kumar, C. V.; Chaudhari, A. J. Am. Chem. Soc. 1994, 116, 403.
19. Clearfield, A., Ed. Inorganic Ion Exchange Materials; CRC Press: Boca Raton, FL, 1982.
20. Ungashe, S. B.; Wilson, W. L.; Katz, H. E.; Scheller, G. R.; Putvinski, T. M. J. Am. Chem. Soc. 1992, 114, 8717. Vermeulen, L. A.; Thompson, M. E. Nature 1992, 358, 656.
21. Ungashe, S. B.; Wilson, W. L.; Katz, H. E.; Scheller, G. R.; Putvinski, T. M. J. Am. Chem. Soc. 1992, 114, 8717. Vermeulen, L. A.; Thompson, M. E. Nature 1992, 358, 656.
22. Clearfield, A. J. Mol. Catal., 1984, 27, 251.
23. Alberti, G.; Casciola, M.; Costantino, U. J. Colloid Interface Sci. 1985, 107, 256.
24. Katz, H. E.; Scheller, G.; Putvinski, T. M.; Schilling, M. L.; Wilson, W. L.; Chidsey, C. E. D. Science 1991, 254, 1485.
25. Kumar, C. V.; Asuncion, E. H.; Rosenthal, G. L. Microporous Mater. 1993, 1, 123.
26. Kumar, C. V.; Asuncion, E. H.; Rosenthal, G. L. Microporous Mater. 1993, 1, 299.
27. Kumar, C. V.; Williams, Z. J.; Kher, F. Microporous Mater. 1996, 7, 161.
28. Vermeulen, L. A.; Snover, J. L.; Sapochak, L. S.; Thompson, M. E. J. Am. Chem. Soc. 1993, 115, 11767.
29. Lehn, J.-M. In Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds.; VCH Publishers: New York, 1991; pp 1. Wasielewski, M. R.; Niemczyk, M. P.; Svec, W. A.; Pewitt, E. B. J. Am. Chem. Soc. 1985, 107, 5562. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
30. Lehn, J.-M. In Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds.; VCH Publishers: New York, 1991; pp 1. Wasielewski, M. R.; Niemczyk, M. P.; Svec, W. A.; Pewitt, E. B. J. Am. Chem. Soc. 1985, 107, 5562. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
31. Lehn, J.-M. In Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds.; VCH Publishers: New York, 1991; pp 1. Wasielewski, M. R.; Niemczyk, M. P.; Svec, W. A.; Pewitt, E. B. J. Am. Chem. Soc. 1985, 107, 5562. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
32. Lehn, J.-M. In Frontiers in Supramolecular Organic Chemistry and Photochemistry; Schneider, H.-J., Durr, H., Eds.; VCH Publishers: New York, 1991; pp 1. Wasielewski, M. R.; Niemczyk, M. P.; Svec, W. A.; Pewitt, E. B. J. Am. Chem. Soc. 1985, 107, 5562. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. Durr, H.; Schwarz, R.; Andreis, C.; Willner, I. J. Am. Chem. Soc. 1994, 115, 12362.
33. Kalyanasundaram, K. Coord. Chem. Rev. 1982, 46, 159. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
34. Kalyanasundaram, K. Coord. Chem. Rev. 1982, 46, 159. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
35. Lin, C-T.; Sutin, N. J. Phys. Chem. 1976, 80, 97. Creutz, C.; Sutin, C. N. Inorg. Chem. 1976, 15, 499. Purugganan, M. D.; Kumar, C. V.; Turro, N. J.; Barton, J. R. Science 1988, 241, 1645.
36. Lin, C-T.; Sutin, N. J. Phys. Chem. 1976, 80, 97. Creutz, C.; Sutin, C. N. Inorg. Chem. 1976, 15, 499. Purugganan, M. D.; Kumar, C. V.; Turro, N. J.; Barton, J. R. Science 1988, 241, 1645.
37. Lin, C-T.; Sutin, N. J. Phys. Chem. 1976, 80, 97. Creutz, C.; Sutin, C. N. Inorg. Chem. 1976, 15, 499. Purugganan, M. D.; Kumar, C. V.; Turro, N. J.; Barton, J. R. Science 1988, 241, 1645.
38. (a) Kuykendall, V. G.; Thomas, J. K. J. Phys. Chem. 1990, 94, 4224.
39. (b) Colon, J. L.; Yang, C-Y.; Clearfield, A.; Martin, C. R. J. Phys. Chem. 1988, 92, 5777.
40. (c) Turro, N. J.; Kumar, C. V.; Grauer, Z.; Barton, J. K. Langmuir 1987, 3, 1056.
41. (d) Vliers, D. P.; Schoonheydt, R. A.; De Schryver, F. C. J. Chem. Soc., Faraday Trans. 1985, 81, 2009.
42. (e) Turro, N. J.; Kumar, C. V.; Grauer, Z.; Barton, J. K. Langmuir 1987, 3, 1056.
43. (f) Pyle, A. M.; Rehmann, J. P.; Meshoyrer, R.; Kumar, C. V.; Turro, N. J.; Barton, J. K. J. Am. Chem. Soc. 1989, 111, 3051.
44. (g) Vliers, D. P.; Collin, D.; Schoonheydt, R. A.; De Schryver, F. C. Langmuir 1986, 2, 165.
45. Kumar, C. V. Abstracts of the North East Regional Meeting of the American Chemical Society, Burlington VT, 1994; Abstracts of the 208th National Meeting of the American Chemical Society; American Chemical Society: Washington, DC, 1994. Kumar, C. V.; Williams. Z. J. J. Phys. Chem. 1995, 99, 17632.
46. Kumar, C. V. Abstracts of the North East Regional Meeting of the American Chemical Society, Burlington VT, 1994; Abstracts of the 208th National Meeting of the American Chemical Society; American Chemical Society: Washington, DC, 1994. Kumar, C. V.; Williams. Z. J. J. Phys. Chem. 1995, 99, 17632.
47. Kumar, C. V. Abstracts of the North East Regional Meeting of the American Chemical Society, Burlington VT, 1994; Abstracts of the 208th National Meeting of the American Chemical Society; American Chemical Society: Washington, DC, 1994. Kumar, C. V.; Williams. Z. J. J. Phys. Chem. 1995, 99, 17632.
48. 2 suspensions for long times resulted in the blue-shifted emission, see: Wheeler, J.; Thomas, J. K. J. Phys. Chem. 1982, 86, 4540. Thomas, J. K. Acc. Chem. Res. 1988, 21, 275.
49. 2 suspensions for long times resulted in the blue-shifted emission, see: Wheeler, J.; Thomas, J. K. J. Phys. Chem. 1982, 86, 4540. Thomas, J. K. Acc. Chem. Res. 1988, 21, 275.
50. Rosenthal, G. L.; Caruso, J. J. Solid State Chem. 1991, 93, 128.
51. 2 g and it is capable of exchanging 5.4 mmol of cationic sites per gm (ecg); see: Wan, B.-Z.; Anthony, R. G.; Peng, B. Z.; Clearfield, A. J. Catal. 1986, 101, 19.
52. Turro, N. J. Modern Molecular Photochemistry: Benjamin/ Cummings: Menlo Park, CA, 1978.
53. Demas, J. N. Excited-State Lifetime Measurements; Academic Press: New York, 1983.
54. β, where α is the preexponential factor, τ is the lifetime, and the value of β varies between 0 and 2. When β = 1, the function reduces to a single exponential and β = 2 it is a product of two exponentials.
55. 2; and F is related to the Franck-Condon factor. See: Miller, J. R.; James, V. B,; Huddleston, R. K. J. Am. Chem. Soc. 1984, 106, 5057. Miller, J. R.; Beitz, J. V. J. Chem. Phys. 1979, 71, 4579.
56. 2; and F is related to the Franck-Condon factor. See: Miller, J. R.; James, V. B,; Huddleston, R. K. J. Am. Chem. Soc. 1984, 106, 5057. Miller, J. R.; Beitz, J. V. J. Chem. Phys. 1979, 71, 4579.
57. Habti, A.; Keravis, D.; Levitz, P.; van Damme, H. J. Chem. Soc., Faraday Trans. II 1984, 80, 67.
58. Ghosh, P. K.; Bard, A. J. J. Phys. Chem. 1984, 88, 5519.
59. Barton, J. K.; Kumar, C. V.; Turro, N. J. J. Am. Chem. Soc. 1986, 108, 6391.
60. Binding of the metal complexes to BAZrP was established in centrifugation studies. When a suspension of BAZrP (0.008 wt %) and metal complexes (10 μM) was allowed to equilibrate for 24 h and centrifuged, yellow-orange solid was collected at the bottom. When the supernatant was tested for free metal complex using absorption spectroscopy, concentration of the metal complex was found to be <0.1 μM.
61. DellaGuardia, R. A.; Thomas, J. K. J. Phys. Chem. 1983, 87, 990.
62. The viscosity of pure ethylene glycol is 19.9 cP and is expected to decrease with the addition of water. Presence of nearly 67% of ethylene glycol did not effect the binding of the metal complexes to BAZrP. This was inferred from the emission maxima which were blue shifted to 590 nm and from centrifugation studies which indicated that the binding was nearly complete.
63. Devault, D. Q. Rev. Biophys. 1980, 13, 387.
64. Closs, G. L.; Piotrowiak, P.; MacInnis, J. M.; Fleming, G. R. J. Am. Chem. Soc. 1988, 110, 2652. Dexter, D. L. J. Chem. Phys. 1953, 21, 836.
65. Closs, G. L.; Piotrowiak, P.; MacInnis, J. M.; Fleming, G. R. J. Am. Chem. Soc. 1988, 110, 2652. Dexter, D. L. J. Chem. Phys. 1953, 21, 836.
66. Miller, J. R. New J. Chem. 1987, 11, 83.
67. Kaufman, K. J.; Dutton, P. L.; Netzel, T. L.; Leigh, S. J.; Rentzepis, P. M. Science 1975, 188, 1301. Van Grondelle, R.; Kramer, J. J.; Rijgersberg, C. P. Biochim. Biophys. Acta 1982, 682, 208. Goedheer, J. C. Biochim. Biophys. Acta 1959, 33, 1.
68. Kaufman, K. J.; Dutton, P. L.; Netzel, T. L.; Leigh, S. J.; Rentzepis, P. M. Science 1975, 188, 1301. Van Grondelle, R.; Kramer, J. J.; Rijgersberg, C. P. Biochim. Biophys. Acta 1982, 682, 208. Goedheer, J. C. Biochim. Biophys. Acta 1959, 33, 1.
69. Kaufman, K. J.; Dutton, P. L.; Netzel, T. L.; Leigh, S. J.; Rentzepis, P. M. Science 1975, 188, 1301. Van Grondelle, R.; Kramer, J. J.; Rijgersberg, C. P. Biochim. Biophys. Acta 1982, 682, 208. Goedheer, J. C. Biochim. Biophys. Acta 1959, 33, 1.