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Tetrahedron

Volumn 35, Issue 21, 1979, Pages 2501-2512

Photolyse de cetones conjuguees heterosubstituees lineaires

(4) Arnould, J C a Enger, A a Feigenbaum, A a Pete, J P a

a Laboratoire de Photochimie1 1 Equipe de Recherche Associé au CNRS No 688 UER Sciences 51062 Reims France ^*

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000742676 PISSN: 00404020 EISSN: None Source Type: Journal
DOI: 10.1016/0040-4020(79)88013-8 Document Type: Article

Times cited : (30)

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- Si l'on admet que le même intermédiaire biradicalaire conduit à la fois aux produits d'élimination (chalcones) et aux produits de cyclisation, la courbe de formation des chalcones, à partir de 4bZ et de 4bE en fonction du nombre de photons absorbés (cf Partie Expérimentale), montre que cette formation est plus rapide a partir de l'isomère Z. Le faible taux de chalcone obtenu à partir de 4bE pour des durées courtes d'irradiation pourrait être le résultat d'une transformation de 4bZ qui apparaîtra rapidement dans le milieu réactionnel.

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