Ground and Excited State Spectroscopic Probes of [(TMP)Fe(IV)=O]+: The First Magnetic Circular Dichroism Study of a Model Peroxidase Compound I Intermediate

Inorganic Chemistry

Volumn 37, Issue 12, 1998, Pages 2842-2843

  Jones, Robert ^a   Jayaraj, Karupiah ^b   Gold, Avram ^b   Kirk, Martin L ^a  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000735228     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970790m     Document Type: Article

References (33)

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21. (b) The C term spectrum is included in the Supporting Information.
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26. 2/Δ4 (Oosterhuis, W. T.; Lang, G. J. Chem. Phys. 1973, 58, 4757-4765.).
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29. P = 1/2) spins.
30. -1.
31. Bill, E.; Ding, X.-Q.; Bominaar, E. L.; Trautwein, A. X.; Winkler, H.; Mandon, D.; Weiss, R.; Gold, A.; Jayaraj, K.; Hatfield, W. E.; Kirk, M. L. Eur. J. Biochem. 1990, 188, 665-672.
32. -1 for simple oxovanadium(IV) and oxochromium(V) complexes; see: Lever, A. B. P. Inorganic Electronic Spectroscopy: Elsevier: New York, 1984; pp 390, 394, and references therein.
33. Jones, R.; Dewitt, J.; Gold, A.; Kirk, M. L. Manuscript in preparation.