Model of tropospheric ion composition: A first attempt

Journal of Geophysical Research Atmospheres

Volumn 105, Issue D18, 2000, Pages 22671-22684

  Beig, G ^a   Brasseur, Guy P ^b,c  

^a INDIAN INSTITUTE OF TROPICAL METEOROLOGY   (India)

^b MAX PLANCK INSTITUTE FOR METEOROLOGY   (Germany)

^c NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL; CLUSTER ANALYSIS; IONIC COMPOSITION; TROPOSPHERE;

EID: 0000734344     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2000JD900119     Document Type: Article

References (50)

1. Arijs, E., Stratospheric ion chemistry: Present understanding and outstanding problems. Planet. Space Sci., 40, 255-270, 1992.
2. Arijs, E., and G. Brasseur, Acetonitrile in the stratosphere and implications for positive ion composition, J. Geophys. Res., 91, 4003-4016, 1986.
3. Arnold, F., Ion nucleation - A potential source for stratospheric aerosols, Nature, 299, 134-137, 1982.
4. Arnold, F., H. Heitmann, and K. Oberfrank, First composition measurements of positive ions in the upper troposphere, Planet. Space Sci., 32., 1567-1576, 1984.
5. Arnold, F., G. Knop, and H. Ziereis, Acetone measurements in the upper troposphere and lower stratosphere - Implications for hydroxyl radical abundances, Nature, 321, 505-507, 1986.
6. Beig, G., and G. Brasseur, Anthropogenic perturbations of tropospheric ion composition, Geophys. Res. Lett., 26, 1303-1306, 1999.
7. Beig, G., S. Walters, and G. Brasseur, A two-dimensional model of ion composition in the stratosphere, 1, Positive ions, J. Geophys. Res., 98, 12,767-12,773, 1993a.
8. Beig, G., S. Walters, and G. Brasseur, A two-dimensional model of ion composition in the stratosphere, 2, Negative ions, J. Geophys. Res., 98, 12,775-12,781, 1993b.
9. Brasseur. G., M. H. Hitchman, S. Walters, M. Dymek, E. Falise, and M. Pirre, An interactive chemical dynamical radiative two-dimensional model of the middle atmosphere, J. Geophys. Res., 95, 5639-5655, 1990.
10. Datta, J., C. P. Revankar, S. C. Chakravarty, and A. P. Mitra, Influence of aerosols on middle atmospheric conductivities, Phys. Scr., 36, 705-710, 1987.
11. Eisele, F. L., Direct tropospheric ion sampling and mass identification, Int. J. Mass Spectrom. Ion Phys., 54, 119-126, 1983.
12. Eisele, F. L., Identification of tropospheric ions, J. Geophys. Res., 91, 7897-7906, 1986.
13. Eisele, F. L., First tandem mass spectrometric measurement of tropospheric ions, J. Geophys. Res., 93, 716-724, 1988.
14. Eisele, F. L., Natural and transmission line produced positive ions, J. Geophys. Res., 94, 6309-6318, 1989a.
15. Eisele, F. L., Natural and anthropogenic negative ions in the troposphere, J. Geophys. Res., 94, 2183-2196, 1989b.
16. Eisele, F. L., and E. W. McDaniel, Mass spectrometric study of tropospheric ions in the northeastern and southwestern United States, J. Geophys. Res., 91, 5183-5188, 1986.
17. Eisele, F. L., and D. J. Tanner, Identification of ions in continental air, J. Geophys. Res., 95, 20, 539-20, 550, 1990.
18. 4 production and loss in the atmosphere, J. Geophys Res., 98, 9001-9010, 1993.
19. Ferguson, E. E., F. C. Fehsenfeld, and D. L. Albritton, Ion chemistry in the Earth's atmosphere, in Gas Phase Ion Chemistry, edited by M. T. Bowers, pp. 45-82, Academic, San Diego, Calif., 1979.
20. Graedel, T. E., Chemical Compounds in the Atmosphere, pp., 440, Academic, San Diego, Calif., 1978.
21. Hamm, S., and P. Warneck, The interhemispheric distribution and the budget of acetonitrile in the troposphere, J. Geophys. Res., 95, 20,593-20,606, 1990.
22. Hauck, G., and F. Arnold, Improved positive ion composition measurements in the upper troposphere and lower stratosphere and the detection of acetone, Nature, 311, 547-550, 1984.
23. Hauglustaine, D. A., G. P. Brasseur, S. Walters, P. J. Rasch, J.-F. Müller, L. K. Emmons, and M. A. Carroll, MOZART, a global chemical trnasport model for ozone and related chemical tracers, 2, Model results and evaluation, J. Geophys. Res., 103, 28,291-28,335, 1998.
24. Heitmann, H., and F. Arnold, Composition measurements of tropospheric ions, Nature, 306, 747-751, 1983.
25. Huertas, M. L., and J. Fontan, Evolution times of tropospheric positive ions, Atmos. Environ., 9, 1018-1026, 1975.
26. Huertas, M. L., J. Fontan, and J. Gonzalez, Evolution times of tropospheric negative ions, Atmos. Environ., 12, 2351-2361, 1978,
27. Ingels, J., D. Nevejans, P. Frederick , and E. Arijs, Acetonitrile and sulfuric acid concentrations derived from ion composition measurements during the MAP/GLOBUS 1983 Campaign, Planet. Space Sci., 35, 685-691, 1987.
28. Jefferson, A., D. J. Tanner, F. L. Eisele, D. D. Davis, G. Chen, J. Crawford, J. W. Huey, A. L. Torres, and H. Berresheim, OH photochemistry and methane sulfonic acid formation in the coastal Antarctic boundary layer, J. Geophys. Res., 103, 1647-1656, 1998.
29. Kawamoto, H., and T. Ogawa, First model of negative ion composition in the troposphere, Planet. Space Sci., 34, 1229-1239, 1986.
30. Knop, G., and F. Arnold, Stratospheric trace gas detection using a new-balloon-borne ACIMS-method: Acetonitrile, acetone, and nitric acid, Geophys. Res. Lett., 14, 1262-1265, 1987.
31. n, J. Atmos. Chem. Soc., 104, 1462-1469, 1982.
32. Luts, A., Evolution of negative small ions at enhanced ionization, J. Geophys. Res., 100, 1487-1496, 1995.
33. Luts, A., Temperature variation of the evolution of positive samll air ions at constant relative humidity, J. Atmos. Terr. Phys., 60, 1739-1750, 1998.
34. Luts, A., and J. Salm, Chemical composition of small atmospheric ions near the ground, J. Geophys. Res., 99, 10,781-10,785, 1994.
35. 4 and MSA during PEM-Tropics A, J. Geophys. Res., 104, 5801-5816, 1999.
36. Mohnen, V. A., Discussion of the formation of major positive and negative ions up to the 50 km level, J. Appl. Geophys., 84, 141-153, 1971.
37. Perkins, M. D., and F. L. Eisele, First mass spectrometric measurements of atmospheric ions at ground level, J. Geophys. Res., 89, 9649-9657, 1984.
38. Rosen, J. M., and D. J. Hofmann, A search for large ions in the stratosphere, J. Geophys. Res., 93, 8415-8422, 1988.
39. Rosen, J. M., D. J. Hofmann, and W. Gringel, Measurements of ion mobility to 30 km, J. Geophys. Res., 90, 5876-5884, 1985.
40. Schlager, H., R. Fabian, and F. Arnold, A new cluster ion source / ion drift cell apparatus for atmospheric ion studies - First mobility and reaction rate coefficient measurements, in Proc. of the 3rd Int. Swarm Seminar, Innsbruck, Austria, pp. 257-262, 1983.
41. Schneider, J., V. Bürger, and F. Arnold, Methyl cyanide and hydrogen cyanide measurements in the lower stratosphere: Implication for methyl cyanide sources and sinks, J. Geophys. Res., 102, 25,501-25,506, 1997.
42. Singh, H. B., D. O'Hara, D. Herlth, W. Sachse, D. R. Blake, J. D. Bradshaw, M. Kanakidou, and P. J. Crutzen, Acetone in the atmosphere: Distribution, sources, and sinks, J. Geophys. Res., 99, 1805-1819, 1994.
43. Snider, J. R., and G. A. Dawson, Surface acetonitrile near Tucson, Arizona, Geophys. Res. Lett., 11, 241-242, 1984.
44. Tanner, D. J., and F. L. Eisele, Ions in oceanic and continental air mass, J. Geophys. Res., 96, 1023-1031, 1991.
45. Turco, R. P., J.-X. Zhao, and F. Yu, A new source of tropospheric aerosols: Ion-ion recombination, Geophys. Res. Lett., 25, 635-638, 1998.
46. 4, J. Geophys. Res., 87, 7340-7342, 1982.
47. 2O) with pyridine and picoline, J. Geophys. Res., 93, 9534-9538, 1988a.
48. n=2-11 with methanol, ammonia, pyridine, acetonitrile and acetone, J. Chem. Phys., 88, 2469-2477, 1988b.
49. Ziereis, H., and F. Arnold, Gaseous ammonia and ammonium ions in the free troposphere, Nature, 321, 503-505, 1986.
50. Yu, F., and R.P. Turco, Ultrafine aerosol formation via ion-mediated nucleation, Geophys. Res. Lett., 27, 883-886, 2000.